Dodecamethylcyclohexasilane undergoes ring contraction with aluminium chloride as catalyst in the presence or absence of trimethylchlorosilane to give, respectively, chlorodimethylsilyl- or trimethylsilyl-cyclo-pentasilane, the former being convertible into monofunctional nonamethylcyclopentasilanes.
M. Ishikawa and M. Kumada, J. Chem. Soc. D, 1969, 567b DOI: 10.1039/C2969000567B
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