Journal cover: Chemical Science

Chemical Science

For findings of exceptional significance from across the chemical sciences – moving to Gold Open Access in 2015
Impact Factor 8.314 12 Issues per Year ALPSP Award for Best New Journal 2011
 
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Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC02305F, Edge Article
A series of responsive porous organic polymers (POPs), UCBZ-1, 2, 3, 4 comprising azobenzene moieties, were synthesized through dynamic imine chemistry and their structure-property relationship was studied. The resulting porous...
 
Kin Long Kelvin Lee, Mitchell Quinn, Alan Maccarone, Klaas Nauta, Paul Houston, Scott A. Reid, Meredith J. T. Jordan and Scott Kable
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC02266A, Edge Article
The correlated speed and rotational energy distributions of the CO fragment from photodissocia-tion of CH3CHO have been measured at a range of wavelengths from 308 to 328 nm. The distri-butions...
 
Lihua Lu, Shiu-Hin Daniel Chan, Daniel W. J. Kwong, Hong-Zhang He, Chung-Hang Leung and Ma Dik-Lung
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC02032D, Edge Article
A series of luminescent Ir(III) complexes were synthesised and evaluated for their ability to act as G-quadruplex-selective probes. A novel Ir(III) complex was found to be highly selective for G-quadruplex...
 
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC01604A, Edge Article
Heteroleptic Ru(II) complexes containing substituted 2,2′:6′,2′′-terpyridine or 2,4-dipyrid-2′-yl-1,3,5-triazine units and the neutral donor 2,6-diguanidylpyridine ligand were synthesized and characterized.
 
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC01567C, Edge Article
The pyrazole and salen ligandosides, when combined, are able to create stable multi-copper ion complexing DNA duplex structures in a cooperative fashion.
 
Dongdong Su, Juwon Oh, Sung-Chan Lee, Jong Min Lim, Srikanta Sahu, Xiaotong Yu, Dongho Kim and Young-Tae Chang
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC01821D, Edge Article
A new set of DRET dyes constructed with a dark donor was designed and investigated by feasibility analysis and theoretical studies.
 
C. Falenczyk, M. Schiedel, B. Karaman, T. Rumpf, N. Kuzmanovic, M. Grøtli, W. Sippl, M. Jung and B. König
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC01346H, Edge Article
Controlling the activity of sirtuins is of high biomedical relevance as the enzymes are involved in cancer, neurodegeneration and other diseases.
 
Wei Wang, Yanyan Zhang, Bin Sun, Li-Jun Chen, Xing-Dong Xu, Ming Wang, Xiaopeng Li, Yihua Yu, Wei Jiang and Hai-Bo Yang
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC01550A, Edge Article
The combination of orthogonal self-assembly and the self-sorting principle affords a novel approach for the construction of multicomponent supramolecular systems.
 
Charlène Esmieu, Maylis Orio, Stéphane Torelli, Laurent Le Pape, Jacques Pécaut, Colette Lebrun and Stéphane Ménage
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC01487A, Edge Article
Through a bio-inspired approach of the active site of the metalloenzyme nitrous oxide reductase, we isolated and characterized a dinuclear mixed-valent dicopper complex capable of N2O reduction at room temperature.
 
Vicente M. Blas-Ferrando, Javier Ortiz, Kei Ohkubo, Shunichi Fukuzumi, Fernando Fernández-Lázaro and Ángela Sastre-Santos
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC01579G, Edge Article
A fully electronically conjugated phthalocyanine–perylenemonoimidebenzimidazole system has been synthesized, in which the conjugation goes through the imide position of the perylene.
 
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC02195A, Edge Article
Dynamics of the ion transport at nanostructured substrate-solution interfaces plays vital roles in high-density energy conversion, stochastic chemical and biosensing, membrane separation, nanofluidics and fundamental nanoelectrochemistry. Further advancements require fundamental...
 
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC02172J, Edge Article
A protocol for palladium-catalyzed ortho C(sp2)–H alkenylation via a rare reported seven-membered palladacycle with oxalyl amide as directing group was reported. The range of olefins were the broadest yet reported...
 
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC02288B, Edge Article
We report the residence time of freely-diffusing, catalytically-active nanoparticles within electron tunnelling distance of a surface. The role of near-wall hindered diffusion is paramount and leads to the new concept...
 
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC01998A, Edge Article
A new azobenzene-based dithiol building block was developed which, upon oxidation, forms predominantly a [2]catenane consisting of two interlocked trimers. In the presence of cyclodextrin templates a series of [2]...
 
Natan J. W. Straathof, Bart J. P. Tegelbeckers, Volker Hessel, Xiao Wang and Timothy Noël
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC01982B, Edge Article
A simple and straightforward photocatalytic trifluoromethylation of thiols allows to prepare a wide variety of SCF3 compounds in batch and continuous-flow.
 
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC01719F, Edge Article
The electronic and structural properties of [Au6{Ni3(CO)6}4]2− pave the way to describe a superatom analogue of the most simple and archetypical hydrocarbon, CH4.
 
Chun-Ting He, Pei-Qin Liao, Dong-Dong Zhou, Bao-Ying Wang, Wei-Xiong Zhang, Jie-Peng Zhang and Xiao-Ming Chen
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC01505C, Edge Article
The interpenetration direction can be more important than the interpenetration number for the porosity, stability, framework flexibility and sorption behavior of MOFs.
 
R. J. Van Hoveln, S. C. Schmid, M. Tretbar, C. T. Buttke and J. M. Schomaker
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC02040E, Edge Article
An enantioselective Cu(I)-catalyzed 1,3-halogen migration reaction accomplishes a formal hydrobromination by transferring a bromine activating group from a sp2 carbon to a benzylic carbon in good er and with concomitant borylation of the Ar–Br bond.
 
Ana Martín-Lasanta, Luis Álvarez de Cienfuegos, Alice Johnson, Delia Miguel, Antonio J. Mota, Angel Orte, Maria Jose Ruedas-Rama, Maria Ribagorda, Diego J. Cárdenas, M. Carmen Carreño, Antonio M. Echavarren and Juan M. Cuerva
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC01988A, Edge Article
Ag(I)–alkyne interactions induce the folding of o-OPE foldamers, yielding a new class of metallofoldamers.
 
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC01901F, Edge Article
This paper describes an efficient method to β-keto methyl sulfones and (E)-vinyl methyl sulfones using DMSO as the substrate. The methyl sulfonyl radical generated from DMSO in the presence of...
 
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC01801J, Edge Article
A balance of metal electrophilicity and ligand steric influences is required for facile, reversible H–H heterolytic cleavage in Mn complexes with pendant amines.
 
Andrea Weiss, Robert H. Berndsen, Maxime Dubois, Cristina Müller, Roger Schibli, Arjan W. Griffioen, Paul J. Dyson and Patrycja Nowak-Sliwinska
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC01255K, Edge Article
Based on the clinical success of platinum-based anti-cancer drugs, a variety of other metal-based anti-cancer compounds are being investigated.
 
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC02090A, Edge Article
Binding of organic guests containing acidic or basic groups inside a water-soluble coordination cage host shows strong pH dependence.
 
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC01811G, Edge Article
We report on a cobalt sulphide (CoS) electrode prepared by simple and scalable chemical bath deposition (CBD), which performs as a highly efficient and robust electrocatalyst for the H2 evolution...
 
Tsuyoshi Suzuki, Takafumi Nakagawa, Kei Ohkubo, Shunichi Fukuzumi and Yutaka Matsuo
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC02018A, Edge Article
A large π-electron conjugated system consisting of bridging three palladium metals and two π-expanded tetracene derivatives was synthesized to have a narrow HOMO–LUMO gap material for long-wavelength light absorption. The...
 

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