Journal cover: Chemical Science

Chemical Science

For findings of exceptional significance from across the chemical sciences
All articles free to read, free to publish* from 2015
*Article processing charges waived for articles published in 2015 and 2016
Impact Factor 8.601 12 Issues per Year Immediacy Index 3.07
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Chem. Sci., 2015, Advance Article
DOI: 10.1039/C5SC90009C, Correction
Yue Zhang, Fangmao Ye, Wei Sun, Jiangbo Yu, I-che Wu, Yu Rong, Yong Zhang and Daniel T Chiu
Chem. Sci., 2015, Accepted Manuscript
DOI: 10.1039/C4SC03959A, Edge Article
This paper describes a synthetic approach for photocrosslinkable polyfluorene (pc-PFO) semiconducting polymer dots, and demonstrates their superior ability to crosslink and form 3-D intermolecular polymer networks. The crosslinked pc-PFO Pdots...
Pablo Rivera-Fuentes, Alexandra T. Wrobel, Melissa L. Zastrow, Mustafa Khan, John Georgiou, Thomas T. Luyben, John C. Roder, Kenichi Okamoto and Stephen J. Lippard
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C4SC03388D, Edge Article
A fluorescent sensor that is pH-insensitive and compatible with two-photon microscopy was developed and applied to live cell and deep tissue imaging.
Sergi Vela, Mercè Deumal, Motoyuki Shiga, Juan J. Novoa and Jordi Ribas-Ariño
Chem. Sci., 2015, Accepted Manuscript
DOI: 10.1039/C4SC03930K, Edge Article
The magnetic properties of molecule-based magnets are commonly rationalized by considering only a single nuclear configuration of the system under study (usually a X- ray crystal structure). Here, by means...
Joel E. Schmidt, Dan Xie, Thomas Rea and Mark E. Davis
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C4SC03935A, Edge Article
CIT-7, a new microporous material that contains 8 and 10-membered rings prepared as a silicate, an aluminosilicate or titanosilicate.
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C4SC03772C, Edge Article
A Ti/Co heterobimetallic complex featuring a very short metal–metal triple bond has been synthesized. This complex promotes the reductive coupling reaction of aryl ketones into alkenes.
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C4SC03614J, Edge Article
Dynamic tracking of pathogenic receptor expression with live cells is made possible by pyrenyl glycoanthraquinones decorated on graphene electrodes.
Vera Krewald, Marius Retegan, Nicholas Cox, Johannes Messinger, Wolfgang Lubitz, Serena DeBeer, Frank Neese and Dimitrios A. Pantazis
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C4SC03720K, Edge Article
A central question in biological water splitting concerns the oxidation states of the manganese ions that comprise the oxygen-evolving complex of photosystem II.
Rafał Szabla, Jesús Campos, Judit E. Šponer, Jiří Šponer, Robert W. Góra and John D. Sutherland
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C4SC03761H, Edge Article
H–D exchange experiments and quantum-chemical calculations elucidate the mechanism of photoinduced anomerisation and nucleobase loss reactions observed in β-2′-deoxycytidine.
P. D. Tran, A. Morozan, S. Archambault, J. Heidkamp, P. Chenevier, H. Dau, M. Fontecave, A. Martinent, B. Jousselme and V. Artero
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C4SC03774J, Edge Article
Bio-inspired chemistry allowed for the development of the first noble metal-free polymer electrolyte membrane hydrogen fuel cell (PEMFC). The device proved operational under technologically relevant conditions.
Hui Wang, Wei Zhu, Jian Li, Tian Tian, Yue Lan, Ning Gao, Chen Wang, Meng Zhang, Charl F. J. Faul and Guangtao Li
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C4SC03278K, Edge Article
Here we report on the use of a self-assembled organic object to template the first example of a nanoscale metal–organic framework (MOF) with a helical morphology.
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C4SC03641G, Edge Article
High-performance illumination of subcutaneous tumor and liver tumor foci was achieved with sialic acid-targeted acid-responsive nanovesicles which become fluorescent and photoacoustic upon internalization into tumor lysosomes.
Bryden Le Bailly, Liam Byrne, Vincent Diemer, Mohammadali Foroozandeh, Gareth A Morris and Jonathan Clayden
Chem. Sci., 2015, Accepted Manuscript
DOI: 10.1039/C4SC03944K, Edge Article
Although foldamers, by definition, are extended molecular structures with a well-defined conformation, minor conformers must be populated at least to some extent in solution. We present a quantitative analysis of...
Miao-Ping Chien, Christopher A. Werley, Samouil L. Farhi and Adam E. Cohen
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C4SC03676J, Edge Article
A new method enables optical selection of one or more cells in culture via photochemical crosslinking to the culture dish.
Chem. Sci., 2015, Accepted Manuscript
DOI: 10.1039/C4SC03960B, Edge Article
In this study, we report the interconvertible tetracolored solid state photoluminescence of gold(I) isocyanide complex 2 upon various external stimuli through solid state structural changes. Soaking the complex of 2...
X. G. Li, Yaozu Liao, Mei-Rong Huang and Richard B Kaner
Chem. Sci., 2015, Accepted Manuscript
DOI: 10.1039/C4SC03890H, Edge Article
A novel polyfluoranthene (PFA) exhibiting strong visual fluorescence emission, a highly amplified quenching effect, and widely controllable electrical conductivity is synthesized by the direct chemical oxidative polymerization of fluoranthene in...
Chem. Sci., 2015, Accepted Manuscript
DOI: 10.1039/C4SC03824J, Edge Article
Unravelling the uniqueness of metal coordination on the biological behaviours is of importance to design metal based therapeutic and diagnostic agents. In this work, we chose luminescent Znsalen (ZnL1) as...
Matthew Bedics, Hayleigh Kearns, Jordan Cox, Samuel Mabbott, Fatima Ali, Neil Shand, Karen Faulds, Jason Benedict, Duncan Graham and Michael Detty
Chem. Sci., 2015, Accepted Manuscript
DOI: 10.1039/C4SC03917C, Edge Article
Surfaced enhanced Raman scattering (SERS) nanotags operating with 1280-nm excitation were constructed from reporter molecules selected from a library of 14 chalcogenopyrylium dyes containing phenyl, 2-thienyl, and 2-selenophenyl substituents and...
Peter M. Marley, Tesfaye A. Abtew, Katie E. Farley, Gregory A. Horrocks, Robert V. Dennis, Peihong Zhang and Sarbajit Banerjee
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C4SC03748K, Edge Article
We report the synthesis of a new tunnel-structured polymorph of V2O5 (ζ-V2O5) synthesized by topotactic ion extraction.
Thomas Just Sørensen, Alan M. Kenwright and Stephen Faulkner
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C4SC03827D, Edge Article
Heterometallic lanthanide complexes can display a ratiometric response to oxygen concentrations.
Yusuke Kawamoto, Asuka Sasaki, Kaori Hashiya, Satoru Ide, Toshikazu Bando, Kazuhiro Maeshima and Hiroshi Sugiyama
Chem. Sci., 2015, Accepted Manuscript
DOI: 10.1039/C4SC03755C, Edge Article
The binding of molecules to specific DNA sequences is important for imaging genome DNA and for studying gene expression. Increasing the number of base pairs targeted by these molecules would...
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C4SC03358B, Edge Article
A Cu(I)-catalyzed denitrogenative transannulation reaction of pyridotriazoles with terminal alkynes en route to indolizines was developed.
Chem. Sci., 2015, Accepted Manuscript
DOI: 10.1039/C5SC00070J, Minireview
Metal nanostructures offer invaluable possibilities for targeted drug delivery, detection/diagnosis and imaging. Whereas iron, gold, silver and platinum nanoachitectures have largely dominated this field to date, several hurdles impede the...
Dan Dumitrescu, Yves-Marie Legrand, Eddy Petit, Arie van der Lee and Mihail Barboiu
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C4SC03945A, Edge Article
Alkane chains may be encapsulated inside rigid crystalline capsules, adopting specific conformations of different levels of compression that are sufficiently kinetically stable under the confined conditions, to allow a conventional structure determination by X-ray diffraction.
Deborah Crawford, José Casaban, Robert Haydon, Nicola Giri, Tony McNally and Stuart L. James
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C4SC03217A, Edge Article
Continuous flow mechanochemical and melt-phase synthesis at kg h−1 rates from solid reagents and either no solvent, or only minimal solvent, is reported.

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