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Chemical Science

For findings of exceptional significance from across the chemical sciences
All articles free to read, free to publish* from 2015
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Impact Factor 9.144 12 Issues per Year
 
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Daniel Görl, Bartolome Soberats, Stefanie Herbst, Vladimir Stepanenko and Frank Würthner
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC02249A, Edge Article
Tuning of the temperature response of perylene bisimide hydrogels exhibiting LCST behavior has been achieved by social self-assembly in water.
 
Mohammad A Haghighatbin, Shih-Chun Lo, Paul Burn and Conor Francis Hogan
Chem. Sci., 2016, Accepted Manuscript
DOI: 10.1039/C6SC01912A, Edge Article
A single component electrochemiluminescence system from which red, green, blue or white emission can be obtained, depending on the applied potential or the mode of the ECL experiment, is described....
 
Ming Li, Sangeeta Ray Banerjee, Chao Zheng, Martin G. Pomper and Ishan Barman
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC01739H, Edge Article
Leveraging optimally engineered SERS tags and urea-based small-molecule inhibitor of PSMA, we report an ultrahigh binding affinity imaging nanoplex for castrate resistant prostate cancer and demonstrate live single cell vibrational spectroscopic imaging at ultralow concentrations.
 
Sergey S. Zalesskiy, Nikita S. Shlapakov and Valentine P. Ananikov
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC02132H, Edge Article
Efficient metal-free photoredox pathway to the thiol–yne click reaction is described using Eosin Y as a catalyst and dedicated 3D-printed photoreactor.
 
S. Katz, J. Noth, M. Horch, H. S. Shafaat, T. Happe, P. Hildebrandt and I. Zebger
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC01098A, Edge Article
Low temperature resonance Raman spectroscopy reveals the initial, transient H-cluster intermediate during biological hydrogen production by [FeFe]-hydrogenase.
 
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC02558G, Edge Article
Lewis acidic fluorinated organoantimony(V) derivatives have been combined with phosphines for the complexation and colourimetric sensing of formaldehyde in biphasic water/CH2Cl2 mixtures.
 
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC02500E, Minireview
Design strategies, response modes and bioapplications of spectroscopic probes are briefly reviewed, which may have important guiding significance for readers.
 
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC02116F, Edge Article
The first example of tantalum nitride electrodes on transparent conductive oxide substrates, which enables solar water splitting, is presented.
 
S. F. Loibl, Z. Harpaz, R. Zitterbart and O. Seitz
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC01883A, Edge Article
This work presents the first method for the rapid chemical total on-resin synthesis of proteins that proceeds without a single HPLC-purification step.
 
Kerstin Freitag, Mariusz Molon, Paul Jerabek, Katharina Dilchert, Christoph Rösler, Rüdiger W. Seidel, Christian Gemel, Gernot Frenking and Roland A. Fischer
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC02106A, Edge Article
Zinc–zinc interactions on nickel and palladium centers are highly dependent on the co-ligands. These dependencies are also found for the formation of dihydrogen vs. dihydride complexes and underline the analogy [Zn2Cp*2] ↔ H2.
 
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC90050J, Correction
 
Xiang Li, Ralph Krafczyk, Jakub Macosek, Yulei Li, Yan Zou, Bernd Simon, Xing Pan, Qiuye Wu, Fang Yan, Janosch Hennig, Kirsten Jung, Jürgen Lassak and Honggang Hu
Chem. Sci., 2016, Accepted Manuscript
DOI: 10.1039/C6SC02889F, Edge Article
A recently discovered posttranslational modification strategy – arginine rhamnosylation – is essential for EF-P dependent rescue of polyproline stalled ribosomes in clinical relevant species such as Pseudomonas aeruginosa, Bordetella pertussis...
 
Chem. Sci., 2016, Accepted Manuscript
DOI: 10.1039/C6SC02451C, Edge Article
A new metal-free oxidative decarbonylative [2+2+2] carbocyclization of N-(2-ethynylaryl)acrylamides with tertiary alkyl aldehydes is described. This reaction enables the formation of three new C-C bonds in a single reaction by...
 
Chem. Sci., 2016, Accepted Manuscript
DOI: 10.1039/C6SC02422J, Edge Article
Photocatalytic alkene synthesis can involve electron and energy transfer processes. The structure of the photocatalyst can be used to control the rate of the energy transfer, providing a mechanistic handle...
 
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC01913G, Edge Article
Trinuclear Re(I)-rings were applied as redox photosensitizers in visible light-driven CO2 reduction in tandem with various catalysts, i.e., Re(I)-, Ru(II)- and Mn(I)-diimine metal complex. The quantum yields for the Ru(II) and Mn(I) catalysts were the among highest reported.
 
Pengzhan Sun, Renzhi Ma, Hui Deng, Zhigong Song, Zhen Zhen, Kunlin Wang, Takayoshi Sasaki, Zhiping XU and Hongwei Zhu
Chem. Sci., 2016, Accepted Manuscript
DOI: 10.1039/C6SC02865A, Edge Article
Although graphene oxide lamellar membranes (GOLMs) are effective in blocking large organic molecules and nanoparticles for nanofiltration and ultrafiltration, water desalination with GOLM is challenging with seriously controversial results. Here,...
 
Hélio Faustino, Maria J. S. A. Silva, Luís F. Veiros, Gonçalo J. L. Bernardes and Pedro M. P. Gois
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC90045C, Correction
 
Dean Howard Barrett, Paul Franklyn, Cristiane Barbieri Rodella, Beatriz Diaz, David Gordon Gordon Billing and Mike Scurrell
Chem. Sci., 2016, Accepted Manuscript
DOI: 10.1039/C6SC01597B, Edge Article
When Au is subdivided to the nanoscale its reactivity changes from an inert nature to one of incredible reactivity which is not replicated by other catalysts. When dispersed onto metal...
 
Chem. Sci., 2016, Accepted Manuscript
DOI: 10.1039/C6SC02343F, Edge Article
The room temperature reaction of a 1:1 mixture of phosphorus tribromide (PBr3) and the N-heterocyclic carbene 1,3-bis(2,6-diisopropylphenyl)-imidazol-2ylidene (IPr) quantitatively affords the Lewis acid–base adduct (IPr)PBr3 (1). Interestingly, when 1 is...
 
Xiaoxia Le, Wei Lu, Jing Zheng, Dingyi Tong, Ning Zhao, Chunxin Ma, He Xiao, Jiawei Zhang, Youju Huang and Tao Chen
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC02354A, Edge Article
Here, we present a novel mechanical stretchable supramolecular hydrogel with a triple shape memory effect at the macro/micro scale.
 
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC02347A, Edge Article
Here we designed and fabricated a self-powered fluorescence display device based on a fast-charging/recharging battery, composed of a Prussian blue (PB) cathode and a magnesium metal anode with a high theoretical redox potential difference.
 
Hanshen Xin, Congwu Ge, Xiaodi Yang, Honglei Gao, Xiaochun Yang and Xike Gao
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC02504H, Edge Article
The first class of azulene-based aromatic diimides, 2,2′-biazulene-1,1′,3,3′-tetracarboxylic diimides (BAzDIs), is presented.
 
Chem. Sci., 2016, Accepted Manuscript
DOI: 10.1039/C6SC01813K, Edge Article
Lithium dendrite growth is a fundamental problem that precludes the practical use of lithium metal batteries. Solid polymer electrolytes (SPEs) have been widely studied to resist the growth of lithium...
 
Verena Pfeifer, Travis Jones, Sabine Wrabetz, Cyriac Massué, Juan-Jesus Velesco-Velez, Rosa Arrigo, Michael Scherzer, Simone Piccinin, Michael Haevecker, Axel Knop-Gericke and Robert Schlögl
Chem. Sci., 2016, Accepted Manuscript
DOI: 10.1039/C6SC01860B, Edge Article
Tremendous effort has been devoted towards elucidating the fundamental reasons for the higher activity of hydrated amorphous Ir III/IV oxyhydroxides (IrOx) in the oxygen evolution reaction (OER) in comparison with...
 
Kai-Bin Li, Na Li, Yi Zang, Guo-Rong Chen, Jia Li, Tony D. James, Xiao-Peng He and He Tian
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC02366E, Edge Article
We demonstrate a foldable, fluorogenic glycoprobe that can recognize and simultaneously crosslink a receptor protein to form unique supramolecular bio-ensembles.
 

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108 citations
A reversible photo-induced instability has been found in mixed-halide photovoltaic perovskites that limits the open circuit voltage in solar cells.
DOI: 10.1039/C4SC03141E
Published: 04 Nov 2014
41 citations
The combination of quantum yield and luminescence quenching measurements provides a method to rapidly characterize the occurrence of chain processes in a variety of photoredox reactions.
DOI: 10.1039/C5SC02185E
Published: 07 Jul 2015
20 citations
This review describes the importance and usefulness of pot-economy and one-pot reactions in current synthetic organic chemistry.
DOI: 10.1039/C5SC02913A
Published: 06 Jan 2016

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