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Chemical Science

For findings of exceptional significance from across the chemical sciences
All articles free to read, free to publish* from 2015
*Article processing charges waived for articles published in 2015 and 2016
Impact Factor 8.601 12 Issues per Year Immediacy Index 3.07
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Daiana Andrea Capdevila, Waldemar Marmisollé, Flroencia Tomasina, Veronica Demicheli, Magdalena Portela, Rafael Radi and Daniel H. Murgida
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC02181A, Edge Article
Cytochrome c (Cyt-c) has been previously shown to participate in cardiolipin (CL) oxidation and, therefore, in mitochondrial membrane permeabilization during the early events of apoptosis. The gain of this function...
Junfeng Xie, Shuang Li, Xiaodong Zhang, Jiajia Zhang, Ruoxing Wang, Hao Zhang, B. C. Pan and Yi Xie
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC02019G, Edge Article
Exploring efficient electrocatalysts for hydrogen production is one of the most promising pathways to face the energy crisis in the new century. Herein, we highlight the metallic molybdenum nitride (MoN)...
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC02288B, Edge Article
Catalytic nano-impacts: near-wall hindered diffusion leads to ‘hydrodynamic adsorption’ of freely-diffusing nanoparticles within electron tunnelling distance of a surface.
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC01967A, Edge Article
Full-dimensional potentials and state couplings were developed for the photodissociation of phenol. We also present multidimensional tunneling calculations at the transition state on the shoulder of the first conical intersection.
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC02155J, Edge Article
The direct α-heteroarylation of tertiary amines has been accomplished via photoredox catalysis to generate valuable benzylic amine pharmacophores.
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC02073A, Edge Article
The Stille-coupling polymerization of a short conjugated polymer with an aliphatic linker was used to demonstrate a prototype in a new class of polymer semiconductor wherein the conjugation segment length...
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC01829J, Edge Article
Cu(I)-substituted metal oxide photocatalysts were prepared by a molten CuCl treatment to wide band gap photocatalysts. The Cu(I)-substituted metal oxide photocatalysts possessed a new absorption band in the visible light...
Wendy Queen, Matthew Hudson, Eric Bloch, Jarad A Mason, Miguel Gonzalez, Jason Lee, David Gygi, Joshua Howe, Kyuho Lee, Tamim Darwish, Michael James, Vanessa K Peterson, Simon Teat, Berend Smit, Jeffrey Neaton, Jeffrey R. Long and Craig M Brown
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC02064B, Edge Article
Analysis of the CO2 adsorption properties of a well-known series of metal-organic frameworks M2(dobdc) (dobdc4−= 2,5-dioxido-1,4-benzenedicarboxylate; M = Mg, Mn, Fe, Co, Ni, Cu, and Zn) is carried out in...
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC02290D, Edge Article
A thermally-reversible inimer was used to confirm the controlled growth of individual branches during self-condensing vinyl atom transfer radical polymerization (ATRP). Segmented hyperbranched polymers were synthesized by ATRP of methyl...
Zhichao Hu, Kui Tan, William P Lustig, Hao Wang, Yonggang Zhao, Zheng Chong, Debasis Banerjee, Thomas J. Emge, Yves J. Chabal and Jing Li
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC02157F, Edge Article
Two new luminescent metal-organic frameworks (LMOFs) were synthesized and examined for use as sensory materials. Very fast and effective sensing of RDX was achieved by vapor detection of a cyclic...
Pengju Ren, Anmin Zheng, Jianping Xiao, Xiulian Pan and Xinhe Bao
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC01996B, Edge Article
Ring current is a fundamental concept to understand the nuclear magnetic resonance (NMR) properties and aromaticity for conjugated systems, such as carbon nanotubes (CNTs). Employing the recently developed gauge including...
Sebastian Wesselbaum, Verena Moha, Markus Meuresch, Sandra Brosinski, Katharina Maria Thenert, Jens Kothe, Thorsten vom Stein, Ulli Englert, Markus Hoelscher, Jürgen Klankermayer and Walter Leitner
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC02087A, Edge Article
The hydrogenation of CO2 to methanol can be achieved by a single molecular organometallic catalyst. Whereas homogeneous catalysts were previously believed to allow the hydrogenation only via formate esters as...
S. Hanessian, O. M. Saavedra, M. A. Vilchis-Reyes, J. P. Maianti, H. Kanazawa, P. Dozzo, R. D. Matias, A. Serio and J. Kondo
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC01626B, Edge Article
We report the synthesis, antibacterial evaluation of fluorine–rRNA contacts revealed by an X-ray co-crystal structure of a series of 4′-deoxy-4′-fluoro neomycin B analogs.
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC01327A, Edge Article
Asymmetric palladium-catalyzed carboamination reactions of aminoalkene substrates provide substituted six-membered heterocycles bearing quaternary stereocenters in good yield and high enantioselectivity.
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC02154A, Edge Article
The syntheses and magnetic properties of six new compounds featuring the radical-bridged dilanthanide complexes [(Cp*2Ln)2(-tppz•)]+ (Ln = Gd (1), Tb, 2; Dy, 3; tppz = 2,3,5,6-tetra(2-pyridyl)pyrazine) and [(Cp*2Ln)2(-tppz•)]– (Ln =...
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC01257G, Edge Article
The Co(I) catalyzed amination of aryl halides with lithium hexamethyldisilazide is reported.
Gang Cheng, Steven C. F. Kui, Wai-Hung Ang, Man-Ying Ko, Pui-Keong Chow, Chun-Lam Kwong, Chi-Chung Kwok, Chensheng Ma, Xiangguo Guan, Kam-Hung Low, Shi-Jian Su and Chi-Ming Che
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC01105H, Edge Article
Practical strongly phosphorescent platinum(II) green to white OLED emitters with bulky tetradentate O^N^C^N ligands.
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC02058H, Edge Article
Ion pairing controls regioselectivity in a Au(I)-catalyzed rearrangement by favoring the more polar product-determining transition state.
Allen F Brooks, Joseph John Topczewski, Naoko Ichiishi, Melanie S Sanford and Peter Scott
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC02099E, Perspective
The last 2-3 years have seen numerous relationships developing between organometallic chemists, fluorine chemists and PET Centers around the world. These collaborations have led to the development of many new...
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC02305F, Edge Article
A series of responsive porous organic polymers (POPs), UCBZ-1, 2, 3, 4 comprising azobenzene moieties, were synthesized through dynamic imine chemistry and their structure-property relationship was studied. The resulting porous...
Kin Long Kelvin Lee, Mitchell Quinn, Alan Maccarone, Klaas Nauta, Paul Houston, Scott A. Reid, Meredith J. T. Jordan and Scott Kable
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC02266A, Edge Article
The correlated speed and rotational energy distributions of the CO fragment from photodissocia-tion of CH3CHO have been measured at a range of wavelengths from 308 to 328 nm. The distri-butions...
Lihua Lu, Shiu-Hin Daniel Chan, Daniel W. J. Kwong, Hong-Zhang He, Chung-Hang Leung and Ma Dik-Lung
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC02032D, Edge Article
A series of luminescent Ir(III) complexes were synthesised and evaluated for their ability to act as G-quadruplex-selective probes. A novel Ir(III) complex was found to be highly selective for G-quadruplex...
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC01604A, Edge Article
Heteroleptic Ru(II) complexes containing substituted 2,2′:6′,2′′-terpyridine or 2,4-dipyrid-2′-yl-1,3,5-triazine units and the neutral donor 2,6-diguanidylpyridine ligand were synthesized and characterized.
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC01567C, Edge Article
The pyrazole and salen ligandosides, when combined, are able to create stable multi-copper ion complexing DNA duplex structures in a cooperative fashion.
Dongdong Su, Juwon Oh, Sung-Chan Lee, Jong Min Lim, Srikanta Sahu, Xiaotong Yu, Dongho Kim and Young-Tae Chang
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC01821D, Edge Article
A new set of DRET dyes constructed with a dark donor was designed and investigated by feasibility analysis and theoretical studies.

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