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Chemical Science

For findings of exceptional significance from across the chemical sciences
All articles free to read, free to publish* from 2015
*Article processing charges waived for articles published in 2015 and 2016
Impact Factor 8.601 12 Issues per Year Immediacy Index 3.07
 
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Frederic A. Perras, William Ewing, Theresa Dellermann, Julian Bohnke, Stefan Ullrich, Thomas Schafer, Holger Braunschweig and David L. Bryce
Chem. Sci., 2015, Accepted Manuscript
DOI: 10.1039/C5SC00644A, Edge Article
There is currently tremendous interest in the previously documented example of a stable species exhibiting a boron-boron triple bond (Science, 2012, 336, 1420). Notably, it has recently been stated using...
 
Sergio Carrasco, Elena Benito-Peña, David R. Walt and María C. Moreno-Bondi
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C5SC00115C, Edge Article
In this article we describe a new class of high-density optical microarrays based on molecularly imprinted microsphere sensors that directly incorporate specific recognition capabilities to detect enrofloxacin (ENRO), an antibiotic widely used for both human and veterinary applications.
 
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C5SC00726G, Edge Article
The formation and isomerisation of nido-[C2B10H12]2− species is investigated through DFT calculations, which reveal novel basket and inverted nido intermediates and unusual inverconversion pathways, including basket collapse and pivoting triangles and diamonds.
 
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C5SC00101C, Edge Article
Biosynthetic pathway intermediates related to genotoxin colibactin formation: a linear compound 3 bearing a rare 7-methyl-4-azaspiro[2.4]hept-6-en-5-one residue.
 
Prinson P. Samuel, Roman Neufeld, Kartik Chandra Mondal, Herbert W. Roesky, Regine Herbst-Irmer, Dietmar Stalke, Serhiy Demeshko, Franc Meyer, Vallyanga Chalil Rojisha, Susmita De, Pattiyil Parameswaran, A. Claudia Stückl, Wolfgang Kaim, Jonathan H. Christian, Jasleen K. Bindra and Naresh S. Dalal
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C5SC00646E, Edge Article
Complexes with two and three coordinate chromium(I).
 
Alan R. Healy, Douglas R. Houston, Lucy Remnant, Anne-Sophie Huart, Veronika Brychtova, Magda M. Maslon, Olivia Meers, Petr Muller, Adam Krejci, Elizabeth A. Blackburn, Borek Vojtesek, Lenka Hernychova, Malcolm D. Walkinshaw, Nicholas J. Westwood and Ted R. Hupp
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C4SC03885A, Edge Article
Discovery and use of a chemical tool.
 
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C5SC00704F, Edge Article
High-resolution state-selective autodetachment photoelectron spectroscopy via dipole-bound states and photodetachment spectroscopy of cryogenically cooled deprotonated thymine anions are reported.
 
Chem. Sci., 2015, Accepted Manuscript
DOI: 10.1039/C4SC03716B, Edge Article
Surface tension, an important property of liquids, is easily measured for bulk samples. However, for droplets smaller than a micron in size, there are currently no reported measurements. In this...
 
Hayato Tsurugi, Akio Hayakawa, Shun Kando, Yoshitaka Sugino and Kazushi Mashima
Chem. Sci., 2015, Accepted Manuscript
DOI: 10.1039/C5SC00721F, Edge Article
We developed a hydrodehalogenation reaction of polyhaloalkanes catalyzed by paddlewheel dimolybdenum complexes in combination with 1-methyl-3,6-bis(trimethylsilyl)-1,4-cyclohexadiene (MBTCD) as a non-toxic H-atom source as well as a salt-free reductant. A mixed-ligated...
 
Wei Hong, Shaoyun Chen, Bin Sun, Mark A Arnould, Yuezhong Meng and Yuning Li
Chem. Sci., 2015, Accepted Manuscript
DOI: 10.1039/C5SC00843C, Edge Article
This study utilized high temperature NMR and matrix-assisted laser desorption/ionization time-of-flight (MALDI-ToF) mass spectrometry to reveal that appreciable amounts of structural defects are present in the diketopyrrolopyrrole (DPP)-quaterthiophene copolymers (PDQT)...
 
Bo He, Jing Dai, Danylo Zherebetskyy, Teresa Chen, Benjamin A Zhang, Simon Teat, Qichun Zhang, Lin-Wang Wang and Yi Liu
Chem. Sci., 2015, Accepted Manuscript
DOI: 10.1039/C5SC00304K, Edge Article
Combining core annulation and peripheral group modification, we have demonstrated a divergent synthesis of a family of highly functionalized coronene derivatives from a readily accessible dichlorodiazaperylene intermediate. Various reactions, such...
 
Chem. Sci., 2015, Accepted Manuscript
DOI: 10.1039/C5SC00835B, Edge Article
An efficient palladium-catalyzed asymmetric hydrogenation of fluorinated aromatic pyrazol-5-ols has been developed via capture of active tautomers. A wide variety of 2,5-disubstituted and 2,4,5-trisubstituted pyrazolidinones have been synthesized with up...
 
Andrew Hartley, Athraa Zaki, Adam McGarrity, Cecile Roberts-Ansart, Andriy Moskalenko, Gareth Jones, Monica Craciun, Saverio Russo, Martin Elliott, J. Emyr Macdonald and D. Dafydd Jones
Chem. Sci., 2015, Accepted Manuscript
DOI: 10.1039/C4SC03900A, Edge Article
Post-translational modification (PTM) modulates and supplements protein functionality. In nature this high precision event requires specific motifs and/or associated modification machinery. To overcome the inherent complexity that hinders PTM’s wider...
 
Chem. Sci., 2015, Accepted Manuscript
DOI: 10.1039/C5SC00584A, Edge Article
In this full article, detailed development of a catalytic decarbonylation of conjugated monoynones to synthesize disubstituted alkynes is described. The reaction scope and limitation has been thoroughly investigated, and a...
 
Chem. Sci., 2015, Accepted Manuscript
DOI: 10.1039/C5SC00213C, Edge Article
Two isostructural porphyrin Zr and Hf metal-organic frameworks (FJI-H6 and FJI-H7) are designedly synthesized, which are constructed from 2.5 nm cubic cages. Notably, they both possess high water and chemical...
 
Marcin Kubisiak, Karolina Zelga, Wojciech Bury, Iwona Justyniak, Krzysztof Budny-Godlewski, Zbigniew Ochal and Janusz Lewiński
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C5SC00600G, Edge Article
A novel organozinc initiator with a clear mechanistic signature for organic radical reactions has been developed.
 
Ken Mukai, Satoshi Kasuya, Yuki Nakagawa, Daisuke Urabe and Masayuki Inoue
Chem. Sci., 2015, Accepted Manuscript
DOI: 10.1039/C5SC00212E, Edge Article
A convergent total synthesis of ouabagenin, an aglycon of cardenolide glycoside ouabain, was achieved by assembly of the AB-ring, D-ring and butenolide moieties. The multiply oxygenated cis-decalin structure of the...
 
Chem. Sci., 2015, Accepted Manuscript
DOI: 10.1039/C5SC00410A, Perspective
van der Waals (vdW) dispersion interactions are a key ingredient in the structure, stability, and response properties of many molecular materials and essential for us to be able to understand...
 
Chris H. Hill, Agnete H. Viuff, Samantha J. Spratley, Stéphane Salamone, Stig H. Christensen, Randy J. Read, Nigel W. Moriarty, Henrik H. Jensen and Janet E. Deane
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C5SC00754B, Edge Article
Modified azasugar molecules have been synthesized and characterized as excellent pharmacological chaperone candidates to treat the neurodegenerative disorder Krabbe disease.
 
Alberto Martinez-Cuezva, Aurelia Pastor, Giacomo Cioncoloni, Raul-Angel Orenes, Mateo Alajarin, Mark D. Symes and Jose Berna
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C5SC00790A, Edge Article
Di(acylamino)pyridine motifs enable the building of switchable interlocked systems in which their dynamics can be exchanged between different states.
 
Dan-Dan Yin, Qi Chen, Yin-Shan Meng, Hao-Ling Sun, Yi-Quan Zhang and Song Gao
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C5SC00491H, Edge Article
2D dysprosium complex exhibiting slow magnetic relaxation originating from the strong Ising anisotropy of single Dy3+ ions has been reported.
 
Mamoru Tobisu, Toshifumi Morioka, Naoto Chatani and Akimichi Ohtsuki
Chem. Sci., 2015, Accepted Manuscript
DOI: 10.1039/C5SC00305A, Edge Article
The reductive cleavage of the C-O bonds of aryl ethers has numerous potential in organic synthesis. Although several catalysts that can promote the reductive cleavage of aryl ethers have been...
 
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C5SC00518C, Edge Article
Ir nanodendrites (Ir-ND) supported on antimony doped tin oxide (ATO) show enhanced catalytic activity and stability for oxygen evolution reaction (OER) in polymer electrolyte membrane (PEM) water electrolysis.
 
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C5SC00357A, Edge Article
Achieving selective C–H functionalization is a significant challenge that requires discrimination between many similar C–H bonds.
 
Chem. Sci., 2015, Advance Article
DOI: 10.1039/C5SC00015G, Edge Article
Platinum(IV) prodrug complexes based on the cisplatin/oxaliplatin pharmacophore, containing anti-HER2/neu targeting peptides, were designed to deliver their cytotoxic platinum(II) payload selectively to highly HER2-expressing cells. Through induction of necrotic cell death, these platinum(IV)–peptide conjugates can circumvent apoptosis-resistance pathways in targeted HER2-positive cells.
 

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