Journal cover: Chemical Science

Chemical Science

A new journal for findings of exceptional significance from across the chemical sciences
Impact Factor 8.314 12 Issues per Year ALPSP Award for Best New Journal 2011
 
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Zil E Huma, Justin Peter Ludeman, Brendan L. Wilkinson, Richard James Payne and Martin Jeremy Stone
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC00131A, Edge Article
We describe a general approach for analysis of 2D NMR spectra to evaluate the cooperativity of ligand binding and protein dimerization in coupled systems. The approach is applicable to systems...
 
Michael Hill, Mathew Anker, Merle Arrowsmith, David Liptrot, Peter Bellham, Catherine Weetman, Gabriele Kociok-Kohn and Mary Mahon
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC00885E, Edge Article
Treatment of beta-diketiminato Mg and Ca amidoborane compounds with B(C6F5)3 induces hydride elimination and formation of alkaline earth hydrido-tris(pentafluorophenyl)borate derivatives. Both species react with CO2 to provide formate complexes, one...
 
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C3SC53211A, Edge Article
A six-station linear guest for cucurbit[7]uril and cucurbit[8]uril has been synthesized in order to implement a cascade of transformations driven by external stimuli.
 
Milica Sentic, Milena Milutinovic, Frédéric Kanoufi, Dragan Manojlovic, Stéphane Arbault and Neso Sojic
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC00312H, Edge Article
Mapping the reactivity of a redox-sensitive luminescent microobject positioned in fluxes of reactive species allows analyzing complex mechanistic processes such as the electrogenerated chemiluminescence of model systems used in immunoassays.
 
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC00860J, Edge Article
The role of hydrotropic counteranions in governing the self-assembled structures of cationic bolaamphiphiles is studied in this work. We reveal that the ability of a hydrotropic counteranion to induce the...
 
Yugang Bai, Hang Xing, Gretchen A. Vincil, Jennifer Lee, Essence Henderson, Yi Lu, Gabriel Lemcoff and Steve Zimmerman
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC00700J, Edge Article
A new approach to prepare functional organic nanoparticles (ONPs) from linear polymers is described. The nanoparticles are obtained by ring-opening metathesis polymerisation (ROMP) of functionalised norbornene dicarboximides, side-chain amidation with...
 
Yang Yang, Zhiqiang Pei, Xiqi Zhang, lei tao, yen wei and Yan Ji
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC00543K, Edge Article
Assembling epoxy, one of the most common and widely used thermosets, by welding with remote control is extremely difficult and has not been realized so far, for epoxy cannot melt...
 
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC00035H, Edge Article
Micelles of surfactant solubilized metal-seamed pyrogallol[4]arene based organic nanocapsules are synthesized and characterized using in situ neutron scattering and dynamic light scattering techniques, which show trends in sizes as a function of alkyl tails of pyrogallols and surfactants.
 
Amit Kumar, Heather C. Johnson, Thomas N. Hooper, Andrew S. Weller, Andrés G. Algarra and Stuart A. Macgregor
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC00735B, Edge Article
Multiple metal-bound oligomers in the dehydropolymerisation of H3B·NH3 have been observed experimentally and the mechanism of oligomerisation probed computationally.
 
Virginie Domalain, Marie Hubert-Roux, Vincent Tognetti, Laurent Joubert, Catherine Lange, Jacques Henri Rouden and Carlos Afonso
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC00443D, Edge Article
The present work describes the first differentiation of enantiomers using the coupling of traveling wave ion mobility and mass spectrometry (TWIM-MS). This study was carried out on amino acids, the...
 
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC00368C, Edge Article
Most copper-catalyzed cross-couplings require an elevated reaction temperature. Recently, a photoinduced variant has been developed that enables C–X bond-forming reactions of certain nitrogen and sulfur nucleophiles to proceed under unusually...
 
Michael Pittelkow, Micke Lisbjerg, Bo Michael Jessen, Brian Rasmussen, Bjarne Nielsen and Anders Østergaard Madsen
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC00990H, Edge Article
The discovery of receptors using templated synthesis enables the selection of strong receptors from complex mixtures. In this contribution we describe a study of the condensation of D-Biotin and formaldehyde...
 
David H. Webber, Jannise J. Buckley, Priscilla D. Antunez and Richard L. Brutchey
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC00749B, Edge Article
Despite their extremely low solubility in most solvents, hexagonal grey selenium and tellurium are shown to be remarkably soluble in binary mixtures of thiols and ethylenediamine (en) at room temperature and ambient pressure.
 
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC00033A, Edge Article
A ratiometric method based on a fluorogenic α-tocopherol analogue reveals oxidation occurring under ambient conditions during liposome preparation.
 
A. Grubman, S. A. James, J. James, C. Duncan, I. Volitakis, J. L. Hickey, P. J. Crouch, P. S. Donnelly, K. M. Kanninen, J. R. Liddell, S. L. Cotman, M. D. de Jonge and A. R. White
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC00316K, Edge Article
XFM approach detects subcellular zinc and calcium mishandling in a fatal neurodegenerative disease, that is corrected by delivery of bioavailable zinc.
 
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC00578C, Edge Article
We develop a method that reveals subcellular localization of a native protein within single cells by treatment with combined selective release of cytosolic proteins and immunostaining.
 
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC00006D, Edge Article
The mechanism of activation of C–F bonds in fluoroarenes using a well-defined niobium(III) imido complex has been investigated.
 
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC00116H, Edge Article
Conformational control of arene-linked dinuclear ruthenium(II) organometallics significantly modulates cytotoxicity toward cancer cells and provides a novel route toward the design of more active and selective anticancer drugs.
 
Benedict M. Gardner, Peter A. Cleaves, Christos E. Kefalidis, Jian Fang, Laurent Maron, William Lewis, Alexander J. Blake and Stephen T. Liddle
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC00182F, Edge Article
Differing reactivities of uranium and thorium complexes are ascribed to stabilisation of the transition state by 5f-orbitals for uranium.
 
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC00143E, Edge Article
A supramolecular organometallic cross-linker triggers a sol–gel (chromonic fluid to hydrogel) transition via non-covalent metallophilic interactions.
 
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC00890A, Edge Article
In fullerenization chemistry, the whittling of carbon units from graphenic all-hexagon systems drives the local structural transformation from a sp2-hybridized composition into a pyramidal-like carbon composition. This chemistry recently observed...
 
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC00230J, Edge Article
Well-defined silica supported W catalysts with the general formula [([triple bond, length as m-dash]SiO)W(NAr)([double bond, length as m-dash]CHtBu)(OR)] (OR = OtBuF9, OtBuF6, OtBuF3, OtBu and OSi(OtBu)3), prepared by grafting bis-alkoxide complexes [W(NAr)([double bond, length as m-dash]CHtBu)(OR)2] on silica dehydroxylated at 700 °C (SiO2(700)), display unexpectedly high activity in comparison with their Mo homologues.
 
Chem. Sci., 2014, Advance Article
DOI: 10.1039/C4SC00569D, Edge Article
Phosphorus(V) tetraazaporphyrins which absorb over the complete UV-visible region have been synthesized for the first time.
 
Hailong Wang, Kang Qian, Dongdong Qi, Wei Cao, Kang Wang, Song Gao and Jianzhuang Jiang
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC00694A, Edge Article
Effective and different inter-molecular interaction between fullerene C60 and tetrapyrrole-based double-decker SMM of three cocrystallates with different molar ratio rationalizes the slight structural change and different magnetic properties. The present...
 
Chem. Sci., 2014, Accepted Manuscript
DOI: 10.1039/C4SC00582A, Minireview
In photosynthetic light harvesting, absorbed photoenergy transfers through networks of pigment-protein complexes to a central location, known as the reaction center, for conversion to chemical energy. This process occurs with...
 

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