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Chemical Science

For findings of exceptional significance from across the chemical sciences
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Chem. Sci., 2017, Advance Article
DOI: 10.1039/C7SC00156H, Edge Article
The ruthenium(II)-catalyzed oxidative cross-coupling of C(sp2)–H bonds with organosilanes has been accomplished for the first time.
Alexandra Roth, Tobias A. Schaub, Ute Meinhardt, Dominik Thiel, Jan Storch, V Cirkva, Pavel Jakubik, Dirk M. Guldi and Milan Kivala
Chem. Sci., 2017, Accepted Manuscript
DOI: 10.1039/C7SC00533D, Edge Article
N,N’-didodecyl-substituted 3,10-diazapicenium salts featuring bromide and hexafluorophosphate counterions have been designed as novel dopants to realize individualized graphene sheets in a series of cutting edge experiments and to intrinsically stabilize...
N S Simpkins and Francois Saint-Dizier
Chem. Sci., 2017, Accepted Manuscript
DOI: 10.1039/C6SC05627J, Edge Article
The synthesis of the unusual alkaloid concavine, isolated from Clitocybe concava (Basidiomycetae), has been accomplished. The synthetic route features a key bridge-forming step involving a new method for sulfenylative radical...
Chem. Sci., 2017, Accepted Manuscript
DOI: 10.1039/C7SC00230K, Edge Article
Manganese-catalyzed sequential C−H and C−C/C−Het bond activation to synthesize allylic alcohols, allylated arenes, functionalized cyclopentenes and skipped dienes is reported. This protocol can be readily scaled up and various coupling...
Fan Cai, Dunfeng Gao, Hu Zhou, Guoxiong Wang, Ting He, Huimin Gong, Shu Miao, Fan Yang, Jianguo Wang and Xinhe Bao
Chem. Sci., 2017, Advance Article
DOI: 10.1039/C7SC90011B, Correction
Chem. Sci., 2017, Advance Article
DOI: 10.1039/C6SC05408K, Edge Article
We found that Ni(OH)2 nanosheets of Ni(OH)2/NOSCF decorated with ∼3.3 nm CeO2 NPs displayed enhanced OER performance.
Zhiwei Qin, John T. Munnoch, Rebecca Devine, Neil A. Holmes, Ryan F. Seipke, Karl A. Wilkinson, Barrie Wilkinson and Matthew I. Hutchings
Chem. Sci., 2017, Advance Article
DOI: 10.1039/C6SC04265A, Edge Article
Ant pharming: antibacterial polyketides from plant-ant associated bacteria.
Chem. Sci., 2017, Advance Article
DOI: 10.1039/C6SC05720A, Edge Article
We demonstrate how a deep neural network (NN) trained on a data set of quantum mechanical (QM) DFT calculated energies can learn an accurate and transferable atomistic potential for organic molecules containing H, C, N, and O atoms.
Chem. Sci., 2017, Advance Article
DOI: 10.1039/C7SC00195A, Edge Article
An innovative new synthesis approach to disubstituted 1,3,4-oxadiazoles is described, inspired by Umpolung Amide Synthesis (UmAS).
Can Wang, Zhiyang Liu, Mengshu Li, Yujun Xie, Bingshi Li, Shuo Wang, Shan Xue, Qian Peng, Bin Chen, Zujin Zhao, Qianqian Li, Ziyi Ge and Zhen Li
Chem. Sci., 2017, Accepted Manuscript
DOI: 10.1039/C6SC05648B, Edge Article
As a promising one in all the well-recognized candidates to solve the coming energy crisis, polymer solar cells (PSCs), perhaps, are the kind of competitive clean energy source. However, as...
Sarah N. Spisak, Andrey Yu. Rogachev, Alexander V. Zabula, Alexander S. Filatov, Rodolphe Clérac and Marina A. Petrukhina
Chem. Sci., 2017, Advance Article
DOI: 10.1039/C6SC05370J, Edge Article
Downsizing of alkali metal belts sandwiched between triply-reduced corannulene decks allows for the fine-tune separation and magnetic coupling of C20H10˙3− radicals.
Chem. Sci., 2017, Accepted Manuscript
DOI: 10.1039/C7SC00100B, Edge Article
In the paper the application of the double radical nucleophilic aromatic substitution (SRN1) in various dihalogenated, mostly diiodinated, π-conjugated systems as a tool for qualitatively estimating their π-conjugation is described....
Yiliang Lin, Yang Liu, Jan Genzer and Michael Dickey
Chem. Sci., 2017, Accepted Manuscript
DOI: 10.1039/C7SC00057J, Edge Article
Stable suspensions of eutectic gallium indium (EGaIn) liquid metal nanoparticles form by probe-sonicating the metal in an aqueous solution. Positively-charged molecular or macromolecular surfactants in the solution, such as cetrimonium...
Chem. Sci., 2017, Accepted Manuscript
DOI: 10.1039/C7SC00468K, Edge Article
The development of a ligand-assisted Pd-catalyzed C–H alkenylation of aliphatic amines is reported. Our studies indicated that an amino-acid-derived ligand renders the C–H bond activation step reversible and promotes the...
Chem. Sci., 2017, Advance Article
DOI: 10.1039/C7SC00033B, Edge Article
The first analytical ab initio potential energy surface reveals the dynamics and different mechanisms of the F + CH3I reaction.
Hannes A. Houck, Kevin De Bruycker, Stijn Billiet, Bastiaan Dhanis, Hannelore Goossens, Saron Catak, Veronique Van Speybroeck, Johan M. Winne and Filip E. Du Prez
Chem. Sci., 2017, Advance Article
DOI: 10.1039/C7SC00119C, Edge Article
An unprecedented relay of triazolinedione-based transclick reactions between three different substrates has been demonstrated both on small molecule and macromolecular level.
Christopher J. Pell, Yanjun Zhu, Rafael Huacuja, David E. Herbert, Russell P. Hughes and Oleg V. Ozerov
Chem. Sci., 2017, Advance Article
DOI: 10.1039/C6SC05391B, Edge Article
The manuscript reports a series of complexes of small perfluorocarbon ligands with the (PNP)Rh fragment, analysis of their electronic structure, and comparison to the hydrocarbon analogues and complexes of CO and NO+.
Sachin R. Chaudhari, John M. Griffin, Katharina Broch, Anne Lesage, Vincent Lemaur, Dmytro Dudenko, Yoann Olivier, Henning Sirringhaus, Lyndon Emsley and Clare P. Grey
Chem. Sci., 2017, Advance Article
DOI: 10.1039/C7SC00053G, Edge Article
DPP-DTT adopts a donor-on-acceptor stacking arrangement which is preserved in thin films.
Chem. Sci., 2017, Advance Article
DOI: 10.1039/C7SC00243B, Edge Article
A catalytic redox system for the direct conjugate addition of pyridines and diazines to Michael acceptors has been developed.
Mónica Giménez-Marqués, Néstor Calvo Galve, Miguel Palomino, Susana Valencia, Fernando Rey, Germán Sastre, Iñigo J. Vitórica-Yrezábal, Mónica Jiménez-Ruiz, J. Alberto Rodríguez-Velamazán, Miguel A. González, José L. Jordá, Eugenio Coronado and Guillermo Mínguez Espallargas
Chem. Sci., 2017, Advance Article
DOI: 10.1039/C6SC05122G, Edge Article
Crystalline materials comprising isolated discrete cavities show preferential gas sorption.
Gabriel Brunet, Damir A. Safin, Mohammad Z. Aghaji, Koen Robeyns, Ilia Korobkov, Tom K. Woo and Muralee Murugesu
Chem. Sci., 2017, Advance Article
DOI: 10.1039/C7SC00267J, Edge Article
The dynamic uptake behaviour of a gaseous guest has been observed crystallographically, yielding a unique and ever-changing set of host–guest interactions that will drive the improvement of high-capacity iodine capture materials.
Shunsuke Kanai, Ippei Nagahara, Yusuke Kita, Keigo Kamata and Michikazu Hara
Chem. Sci., 2017, Advance Article
DOI: 10.1039/C6SC05642C, Edge Article
A CePO4 catalyst exhibits high catalytic performance for the chemoselective acetalization of 5-hydroxymethylfurfural with alcohols, in sharp contrast to other homogeneous and heterogeneous acid and/or base catalysts.
Anastasia V. Bochenkova, Ciarán R. S. Mooney, Michael A. Parkes, Joanne L. Woodhouse, Lijuan Zhang, Ross Lewin, John M. Ward, Helen C. Hailes, Lars H. Andersen and Helen H. Fielding
Chem. Sci., 2017, Advance Article
DOI: 10.1039/C6SC05529J, Edge Article
By uncovering the mechanism of UV resonant electron emission, we show that the GFP biomimetics are more stable to photooxidation.
Marisa Nakada, Takuya Kuwabara, Shunsuke Furukawa, Masahiko Hada, Mao Minoura and Masaichi Saito
Chem. Sci., 2017, Advance Article
DOI: 10.1039/C6SC04843A, Edge Article
An anionic ruthenocene with an η5-coordinating plumbole ligand was prepared and reacted with electrophiles to afford plumbole complexes.
Julien Warnan, Janina Willkomm, Jamues N. Ng, Robert Godin, Sebastian Prantl, James R. Durrant and Erwin Reisner
Chem. Sci., 2017, Advance Article
DOI: 10.1039/C6SC05219C, Edge Article
A series of diketopyrrolopyrrole (DPP) dyes with a terminal phosphonic acid group for attachment to metal oxide surfaces were synthesised and the effect of side chain modification on their properties investigated.

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57 citations
Direct splitting of pure water into H2 and O2 in a stoichiometric molar ratio of 2 : 1 by conjugated polymers via a 4-electron pathway was established for the first time, as demonstrated here using a g-C3N4 polymer and redox co-catalysts of Pt and Co species.
DOI: 10.1039/C5SC04572J
Published: 27 Jan 2016
87 citations
The combination of quantum yield and luminescence quenching measurements provides a method to rapidly characterize the occurrence of chain processes in a variety of photoredox reactions.
DOI: 10.1039/C5SC02185E
Published: 07 Jul 2015
52 citations
This review describes the importance and usefulness of pot-economy and one-pot reactions in current synthetic organic chemistry.
DOI: 10.1039/C5SC02913A
Published: 06 Jan 2016

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