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Chemical Science

For findings of exceptional significance from across the chemical sciences
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Impact Factor 9.144 12 Issues per Year
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Jingnan Zhang, Hui Kang, Nan Li, Shiming Zhou, Huaming Sun, Shiwei Yin, Na Zhao and Ben Zhong Tang
Chem. Sci., 2016, Accepted Manuscript
DOI: 10.1039/C6SC02875F, Edge Article
Organic solid fluorophores with tunable emission color have been widely applied in multiple areas. However, rational design and efficient crafting of these fluorophores from the simple core skeleton is still...
Jimin P Kim, Zhiwei Xie, Michael H Creer, Zhiwen Liu and Jian Yang
Chem. Sci., 2016, Accepted Manuscript
DOI: 10.1039/C6SC02962K, Edge Article
Chloride is an essential electrolyte that maintains homeostasis within the body, where abnormal chloride levels in biological fluids may indicate various diseases such as Cystic Fibrosis. However, current analytical solutions...
Chem. Sci., 2016, Accepted Manuscript
DOI: 10.1039/C6SC03350D, Edge Article
Nanosheets with atomic layer thickness have attracted much interest because of the characteristic properties originating from the anisotropic and flexible structures. Inorganic nanosheets are synthesized from the precursor layered compounds...
Chem. Sci., 2016, Accepted Manuscript
DOI: 10.1039/C6SC03450K, Edge Article
Degree of CO2 activation was tuned by incorporating a distinct electronic coordination environment of a nickel center. By preparing a mononuclear nickel carboxylate species (Ni-CO2, 3) and a dinuclear nickel-iron...
Nichola A. Smith, Pingyu Zhang, Simon E. Greenough, Michael D. Horbury, Guy J. Clarkson, Daniel McFeely, Abraha Habtemariam, Luca Salassa, Vasilios G. Stavros, Christopher G. Dowson and Peter J. Sadler
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC03028A, Edge Article
The Ru(II) complex, cis-[Ru(bpy)2(INH)2]2+ is inactive in the dark but highly active towards mycobacteria on photoactivation with visible light when it releases the antituberculosis drug isoniazid (INH).
Chem. Sci., 2016, Accepted Manuscript
DOI: 10.1039/C6SC02456D, Edge Article
Development of non-noble metal catalysts with activity and stability as noble metals is of significant importance in the conversion and utilization of clean energies. The catalytic hydrolysis of ammonia borane...
Michael R Wasielewski, Rebecca Joy Lindquist, Marek B Majewski, William L Hoffeditz, Brian T Phelan, Omar Farha and J T Hupp
Chem. Sci., 2016, Accepted Manuscript
DOI: 10.1039/C6SC02477G, Edge Article
The design of efficient hydrogen-evolving photocathodes for dye-sensitized photoelectrochemical cells (DSPECs) requires the incorporation of molecular light absorbing chromophores that are capable of delivering reducing equivalents to molecular proton reduction...
Chem. Sci., 2016, Accepted Manuscript
DOI: 10.1039/C6SC03478K, Edge Article
The origins of the stereodivergence in the thioester oxy-Michael cyclization for the formation of 4-hydroxy-2,6-cis- or 2,6-trans-substituted tetrahydropyran rings under different conditions was investigated both computationally and experimentally. Synthetic studies...
Sudipta Raha Roy, Hendrik Eijsberg, Jeffrey Bruffaerts and Ilan Marek
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC02617F, Edge Article
We functionalize cyclobutene species into polysubstituted metalated cyclobutanes through the Dzhemilev reaction.
Thomas H. Pillow, Jack D. Sadowsky, Donglu Zhang, Shang-Fan Yu, Geoffrey Del Rosario, Keyang Xu, Jintang He, Sunil Bhakta, Rachana Ohri, Katherine R. Kozak, Edward Ha, Jagath R. Junutula and John A. Flygare
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC01831A, Edge Article
A novel bioconjugation strategy utilizes a disulfide bond to site-specifically couple a small molecule drug to an antibody, enabling both high circulation stability and quick intracellular release.
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC02045C, Edge Article
GTP hydrolysis in hGBP1 occurs via indirect substrate-assisted catalysis involving a complex proton relay mechanism of concerted-dissociative nature.
Goutham Kodali, Joshua A. Mancini, Lee A. Solomon, Tatiana V. Episova, Nicholas Roach, Christopher J. Hobbs, Pawel Wagner, Olga A. Mass, Kunche Aravindu, Jonathan E. Barnsley, Keith C. Gordon, David L. Officer, P. Leslie Dutton and Christopher C. Moser
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC02417C, Edge Article
Design of nanometer scale artificial light harvesting and charge separating proteins enables reengineering to overcome the limitations of natural selection for efficient systems that better meet human energetic needs.
Runli Tang, Shengmin Zhou, Ziyao Cheng, Gui Yu, Qian Peng, Huiyi Zeng, Guocong Guo, Qianqian Li and Zhen Li
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC02956F, Edge Article
Four Janus NLO dendrimers were intelligently designed and synthesized with largely enhanced NLO performance.
Jan Maciejewski, Adam Sobczuk, Alexis Claveau, Adrien Nicolai, Riccardo Petraglia, Luca Cervini, Emilie Baudat, Pascal Miéville, Daniele Fazzi, Clemence Corminboeuf and Giuseppe Sforazzini
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC03196J, Edge Article
The conjugation of a bithiophene was reversibly modulated over several cycles through the isomerization of an azobenzene.
Song Guo, Tianci Huang, Shujuan Liu, Kenneth Yin Zhang, Huiran Yang, Jianmei Han, Qiang Zhao and Wei Huang
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC02837C, Edge Article
A class of luminescent ion pairs with tunable emission colors was designed and synthesized for light-emitting devices and electrochromic switches.
Fernando Cacho-Bailo, Ismael Matito-Martos, Julio Perez-Carbajo, Miren Etxeberría-Benavides, Oğuz Karvan, Víctor Sebastián, Sofía Calero, Carlos Téllez and Joaquín Coronas
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC02411D, Edge Article
A zeolitic imidazolate framework two-layered membrane approach is simulated and experimentally validated to improve the pre-combustion gas separation.
Simon Pascal, Sandrine Denis-Quanquin, Florence Appaix, Alain Duperray, Alexei Grichine, Boris Le Guennic, Denis Jacquemin, Jérôme Cuny, San-Hui Chi, Joseph W. Perry, Boudewijn van der Sanden, Cyrille Monnereau, Chantal Andraud and Olivier Maury
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC02488B, Edge Article
The keto-heptamethine family has been expanded to various symmetrical and asymmetrical structures.
Adam J. Jackson, Davide Tiana and Aron Walsh
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC90058E, Correction
Chem. Sci., 2016, Accepted Manuscript
DOI: 10.1039/C6SC03109A, Edge Article
A reagent-controlled enantioselectivity switch was uncovered in asymmetric α-fluorination of β-ketocarbonyls by a chiral primary amine catalyst. By a simple swap of fluorination reagents, both enantiomers of quaternary fluorination adducts...
Avelino Corma, Antonio Leyva-Perez, Jose R Cabrero-Antonino, Maria Tejeda, Manuel Quesada and ALEJANDRO VIDAL MOYA
Chem. Sci., 2016, Accepted Manuscript
DOI: 10.1039/C6SC03335K, Edge Article
A new approach is presented to form self–supported bimetallic nanosized solids with acid and redox catalytic properties. They are water–, air– and H2–stable, and are able to activate demanding C–C...
Haiyan Zheng, Lijuan Wang, Kuo Li, Youyou Yang, Yajie Wang, Jiajia Wu, Xiao Dong, Chun-Hai Wang, Christopher A. Tulk, Jamie J. Molaison, Ilia N. Ivanov, Mikhail Feygenson, Wenge Yang, Malcolm Guthrie, Yusheng Zhao, Ho-Kwang Mao and Changqing Jin
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC02830F, Edge Article
Pressure induced polymerization of CaC2 in the amorphous phase is evidenced for the first time, accompanied by a 107 fold enhancement of the electrical conductivity.
Sylwia Walczak, Anna Nowicka, Dorota Kubacka, Kaja Fac, Przemyslaw Wanat, Seweryn Mroczek, Joanna Kowalska and Jacek Jemielity
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC02437H, Edge Article
A different approach for synthesizing 5′ cap mimics to yield a novel class of dinucleotide cap analogues containing a triazole ring within the oligophosphate chain.
Yan Duan, João C. Waerenborgh, Juan M. Clemente-Juan, Carlos Giménez-Saiz and Eugenio Coronado
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC01919F, Edge Article
A new iron-oxalato polyoxometalate exhibits a remarkable photocoloration effect in the solid state based entirely on an intramolecular process.
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC01814A, Edge Article
We designed the first method to systematically investigate cell surface glycoprotein dynamics and measure their half-lives.
Eva Pump, Jasmine Viger-Gravel, Edy Abou-Hamad, Manoja K. Samantaray, Bilel Hamzaoui, Andrei Gurinov, Dalaver H. Anjum, David Gajan, Anne Lesage, Anissa Bendjeriou-Sedjerari, Lyndon Emsley and Jean-Marie Basset
Chem. Sci., 2016, Advance Article
DOI: 10.1039/C6SC02379G, Edge Article
Reactive surface species immobilized inside porous materials with suitably small windows can be studied by DNP SENS.

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116 citations
A reversible photo-induced instability has been found in mixed-halide photovoltaic perovskites that limits the open circuit voltage in solar cells.
DOI: 10.1039/C4SC03141E
Published: 04 Nov 2014
47 citations
The combination of quantum yield and luminescence quenching measurements provides a method to rapidly characterize the occurrence of chain processes in a variety of photoredox reactions.
DOI: 10.1039/C5SC02185E
Published: 07 Jul 2015
21 citations
This review describes the importance and usefulness of pot-economy and one-pot reactions in current synthetic organic chemistry.
DOI: 10.1039/C5SC02913A
Published: 06 Jan 2016

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