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Unusual iron-iron and ruthenium-ruthenium single bonds doubly bridged by two Cu(PR3) fragments: syntheses of iron-copper, iron-silver, and ruthenium-copper heterometallic complexes and structures of M2(CO)8(.mu.-CuPCy3)2 (M = Fe, Ru), [PPh4][Fe2(CO)8(.mu.-CuPCy3)], and [PPh4]2{[Fe2(CO)8]2[.mu.4-.eta.2-Cu2(Cy2PCH2CH2PCy2)]} |
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