Issue 29, 2012
From the journal:

Dalton Transactions

Synthesis and X-ray structure of ruthenium bis(acetylacetonate)(N,N,N′,N′-tetramethylethylenediamine)†‡

Robert L. Halbach,a   Grégory Noctona  and  Richard A. Andersen*a  

* Corresponding authors

a Department of Chemistry and Chemical Science Division of Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720, USA
E-mail: raandersen@lbl.gov

Abstract

Although several ruthenium complexes of the type Ru(acac)2(L)x, where x is 1 for a bidentate or 2 for a monodentate ligand, are known, the tmed complex is conspicuously absent. This article describes the synthesis of this complex from trans-RuCl2(tmed)2, acetylacetone, and triethylamine in toluene. A new synthesis of trans-RuCl2(tmed)2 is also described. Some physical properties and the X-ray crystal structure of Ru(acac)2(tmed) are provided.

Graphical abstract: Synthesis and X-ray structure of ruthenium bis(acetylacetonate)(N,N,N′,N′-tetramethylethylenediamine)

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Article information

DOI
https://doi.org/10.1039/C2DT30810J
Article type
Paper
Submitted
14 Apr 2012
Accepted
04 May 2012
First published
16 May 2012

Dalton Trans., 2012,41, 8809-8812

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Synthesis and X-ray structure of ruthenium bis(acetylacetonate)(N,N,N′,N′-tetramethylethylenediamine)

R. L. Halbach, G. Nocton and R. A. Andersen, Dalton Trans., 2012, 41, 8809 DOI: 10.1039/C2DT30810J

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