Issue 40, 2010
From the journal:

Chemical Communications

Robust photocatalytic waterreduction with cyclometalated Ir(iii) 4-vinyl-2,2′-bipyridine complexes†‡

Stefan Metza  and  Stefan Bernhard*a  

* Corresponding authors

a Carnegie Mellon University, Department of Chemistry, 4400 5th Ave, Pittsburgh, USA
E-mail: bern@cmu.edu
Fax: +1 412-268-1061
Tel: +1 412-268-7419

Abstract

Novel [Ir(C⁁N)2(N⁁N)]+ complexes with N⁁N ligands containing vinyl groups were synthesized resulting in quintupled turn-over numbers for the photocatalytic hydrogen production compared to the analogous non-vinyl compounds.

Graphical abstract: Robust photocatalytic water reduction with cyclometalated Ir(iii) 4-vinyl-2,2′-bipyridine complexes

  • This article is part of the themed collection: Hydrogen
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Article information

DOI
https://doi.org/10.1039/C0CC01827A
Article type
Communication
Submitted
10 Jun 2010
Accepted
25 Aug 2010
First published
17 Sep 2010

Chem. Commun., 2010,46, 7551-7553

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Robust photocatalytic water reduction with cyclometalated Ir(III) 4-vinyl-2,2′-bipyridine complexes

S. Metz and S. Bernhard, Chem. Commun., 2010, 46, 7551 DOI: 10.1039/C0CC01827A

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