Oxidative addition of the bismuth-chloride bond: synthesis and structure of trans-[PtCl(PCy3)2{BiCl2}]

Holger Braunschweig; Peter Brenner; Paul Cogswell; Katharina Kraft; Katrin Schwab

doi:10.1039/C0CC00639D

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Oxidative addition of the bismuth-chloride bond: synthesis and structure of trans-[PtCl(PCy₃)₂{BiCl₂}]†

Holger Braunschweig,*^a Peter Brenner,^a Paul Cogswell,^ab Katharina Kraft^a and Katrin Schwab^a

Author affiliations

* Corresponding authors

^a Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany
E-mail: h.braunschweig@mail.uni-wuerzburg.de
Fax: +49 931 888 4623
Tel: +49 931 31 85260

^b Department of Chemistry, Durham University, South Road, Durham, UK

Abstract

The synthesis and full characterisation of trans-[PtCl(PCy₃)₂{BiCl₂}] is reported via the oxidative addition of the bismuth-chloride bond across [Pt(PCy₃)₂]; this represents the first instance of such an oxidative addition reaction to be undertaken by a bismuth halide bond.

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Supplementary files

Crystal structure data TXT (31K)

Article information

DOI: https://doi.org/10.1039/C0CC00639D
Article type: Communication
Submitted: 29 Mar 2010
Accepted: 11 Jun 2010
First published: 30 Jun 2010

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Chem. Commun., 2010,46, 7894-7896

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Oxidative addition of the bismuth-chloride bond: synthesis and structure of trans-[PtCl(PCy₃)₂{BiCl₂}]

H. Braunschweig, P. Brenner, P. Cogswell, K. Kraft and K. Schwab, Chem. Commun., 2010, 46, 7894 DOI: 10.1039/C0CC00639D

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