Issue 8, 2004
From the journal:

Chemical Communications

A novel methodology for the synthesis of complexes containing long carbon chains linking metal centres: molecular structures of {Ru(dppe)Cp*}2(μ-C14) and {Co3(μ-dppm)(CO)7}2(μ3:μ3-C16)†

Alla B. Antonova,ab   Michael I. Bruce,a   Benjamin G. Ellis,a   Maryka Gaudio,a   Paul A. Humphrey,a   Martyn Jevric,a   Giovanni Melino,a   Brian K. Nicholson,c   Gary J. Perkins,a   Brian W. Skelton,d   Bronwin Stapleton,a   Allan H. Whited  and  Natasha N. Zaitsevaa  

a Department of Chemistry, University of Adelaide, Adelaide, South Australia 5005, Australia

b Institute of Chemistry and Chemical Technology, Russian Academy of Sciences, Krasnoyarsk 660049, Russia

c Department of Chemistry, University of Waikato, Private Bag 3105, Hamilton, New Zealand

d Department of Chemistry, University of Western Australia, Crawley, Western Australia 6009, Australia

Abstract

Elimination of AuX(PR3) (X = halogen, R = Ph, tol) occurs readily in reactions between compounds containing C(sp)– or C(sp2)–X bonds and alkynyl or polyynyl gold(I) complexes; this reaction has been applied to the syntheses of complexes containing a variety of metal centres linked by Cn chains (n up to 16).

Graphical abstract: A novel methodology for the synthesis of complexes containing long carbon chains linking metal centres: molecular structures of {Ru(dppe)Cp*}2(μ-C14) and {Co3(μ-dppm)(CO)7}2(μ3:μ3-C16)

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Article information

DOI
https://doi.org/10.1039/B315854N
Article type
Communication
Submitted
04 Dec 2003
Accepted
04 Feb 2004
First published
08 Mar 2004

Chem. Commun., 2004, 960-961

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A novel methodology for the synthesis of complexes containing long carbon chains linking metal centres: molecular structures of {Ru(dppe)Cp*}2(μ-C14) and {Co3(μ-dppm)(CO)7}2(μ3:μ3-C16)

A. B. Antonova, M. I. Bruce, B. G. Ellis, M. Gaudio, P. A. Humphrey, M. Jevric, G. Melino, B. K. Nicholson, G. J. Perkins, B. W. Skelton, B. Stapleton, A. H. White and N. N. Zaitseva, Chem. Commun., 2004, 960 DOI: 10.1039/B315854N

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