SCHEDULED MAINTENANCE
The adsorption of nitrogen on silica-supported iridium has been studied by infra-red spectroscopy. A band at 2185 cm–1 was observed on “bare” iridium and is assigned to a species of chemisorbed nitrogen with the electronic structure [graphic omitted]. Heats of adsorption for this species (2-4 kcal/mole) have been estimated from the variation of band intensity with temperature at constant pressure.
A. Ravi, D. A. King and N. Sheppard, Trans. Faraday Soc., 1968, 64, 3358 DOI: 10.1039/TF9686403358
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