A deprotection strategy of a BODIPY conjugated porous polymer to obtain a heterogeneous (dipyrrin)(bipyridine)ruthenium(II) visible light photocatalyst

Marta Liras; Mercedes Pintado-Sierra; Marta Iglesias; Félix Sánchez

doi:10.1039/C6TA07696C

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A deprotection strategy of a BODIPY conjugated porous polymer to obtain a heterogeneous (dipyrrin)(bipyridine)ruthenium(ii) visible light photocatalyst†

Marta Liras,‡*^a Mercedes Pintado-Sierra,^a Marta Iglesias^b and Félix Sánchez^a

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* Corresponding authors

^a Instituto de Química Orgánica General (IQOG-CSIC), Juan de la Cierva, 3, 28006 Madrid, Spain

^b Instituto de Ciencia de Materiales de Madrid (ICMM-CSIC), Sor Juana Inés de la Cruz, 3, 28049 Madrid, Spain

Abstract

This work shows that a deprotection strategy of BODIPY conjugated porous polymers (CMPBDPs) can be successfully applied to synthesize a new (dipyrrin)(bipyridine)Ru(II) (CMPBDP-Ru) efficient heterogeneous photocatalyst for iminium ion generation under visible light. CMPBDP-Ru shows high thermal and photochemical stability under irradiation, and it could be reused several times.

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Article information

DOI: https://doi.org/10.1039/C6TA07696C
Article type: Communication
Submitted: 06 Sep 2016
Accepted: 10 Oct 2016
First published: 10 Oct 2016

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J. Mater. Chem. A, 2016,4, 17274-17278

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A deprotection strategy of a BODIPY conjugated porous polymer to obtain a heterogeneous (dipyrrin)(bipyridine)ruthenium(II) visible light photocatalyst

M. Liras, M. Pintado-Sierra, M. Iglesias and F. Sánchez, J. Mater. Chem. A, 2016, 4, 17274 DOI: 10.1039/C6TA07696C

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Journal of Materials Chemistry A

A deprotection strategy of a BODIPY conjugated porous polymer to obtain a heterogeneous (dipyrrin)(bipyridine)ruthenium(ii) visible light photocatalyst†

Abstract

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A deprotection strategy of a BODIPY conjugated porous polymer to obtain a heterogeneous (dipyrrin)(bipyridine)ruthenium(II) visible light photocatalyst

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