Issue 18, 2015
From the journal:

Journal of Materials Chemistry A

Synthesis of a calcium-bridged siloxene by a solid state reaction for optical and electrochemical properties†

Haruo Imagawa,*a   Naoko Takahashi,a   Takamasa Nonaka,a   Yuichi Kato,a   Kazutaka Nishikawaa  and  Hiroshi Itaharaa  

* Corresponding authors

a Toyota Central R&D Labs., Inc., Nagakute, Aichi, 480-1192 Japan
E-mail: e1152@mosk.tytlabs.co.jp

Abstract

A Ca-bridged siloxene (Ca-siloxene) resulting from the deintercalation of Ca from CaSi2 was synthesized via a solid state reaction with ethanol wash using TaCl5. The presence of fragmented, two-dimensional siloxene planes with Ca bridging was confirmed. The Ca-siloxene exhibited tunable optical properties, as well as stable Li storage performance by Ca bridging.

Graphical abstract: Synthesis of a calcium-bridged siloxene by a solid state reaction for optical and electrochemical properties

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5TA00321K
Article type
Communication
Submitted
15 Jan 2015
Accepted
24 Mar 2015
First published
07 Apr 2015

J. Mater. Chem. A, 2015,3, 9411-9414

Author version available

Download author version (PDF)

Permissions

Request permissions

Synthesis of a calcium-bridged siloxene by a solid state reaction for optical and electrochemical properties

H. Imagawa, N. Takahashi, T. Nonaka, Y. Kato, K. Nishikawa and H. Itahara, J. Mater. Chem. A, 2015, 3, 9411 DOI: 10.1039/C5TA00321K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements