Issue 15, 2014

Nitrogen-enriched and hierarchically porous carbon macro-spheres – ideal for large-scale CO2 capture

Abstract

A facile and efficient “spheridization” method is developed to produce nitrogen-enriched hierarchically porous carbon spheres of millimeters in diameter, with intricate micro-, meso- and macro-structural features. Such spheres not only show exceptional working capacity for CO2 sorption, but also satisfy practical requirements for dynamic flow in post-combustion CO2 capture. Those were achieved using co-polymerized acrylonitrile and acrylamide as the N-enriched carbon precursor, a solvent-exchange process to create hierarchically porous macro-sphere preforms, oxidization to induce cyclization of the polymer chains, and carbonization with concurrent chemical activation by KOH. The resulting carbon spheres show a relatively high CO2 uptake of 16.7 wt% under 1 bar of CO2 and, particularly, an exceptional uptake of 9.3 wt% under a CO2 partial pressure of 0.15 bar at 25 °C. Subsequent structural and chemical analyses suggest that the outstanding properties are due to highly developed microporous structures and the relatively high pyridinic nitrogen content inherited from the co-polymer precursor, incorporated within the hierarchical porous structures.

Graphical abstract: Nitrogen-enriched and hierarchically porous carbon macro-spheres – ideal for large-scale CO2 capture

Supplementary files

Article information

Article type
Paper
Submitted
24 Jan 2014
Accepted
25 Feb 2014
First published
26 Feb 2014
This article is Open Access
Creative Commons BY license

J. Mater. Chem. A, 2014,2, 5481-5489

Author version available

Nitrogen-enriched and hierarchically porous carbon macro-spheres – ideal for large-scale CO2 capture

B. Zhu, K. Li, J. Liu, H. Liu, C. Sun, C. E. Snape and Z. Guo, J. Mater. Chem. A, 2014, 2, 5481 DOI: 10.1039/C4TA00438H

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