Soluble conducting polymer-functionalized graphene oxide for air-operable actuator fabrication

Abstract

An effective route for the preparation of a processable, conducting polymer-functionalized graphene oxide for actuator applications is investigated. First, graphene oxide (GO) is covalently functionalized with a 3-thiophene acetic acid (TAA) monomer by an esterification reaction. Then, the TAA-functionalized GO is self-polymerized by chemical oxidative polymerization to yield poly(3-thiophene acetic acid)-functionalized GO (GO-f-PTAA). Further, the GO-f-TAA is also copolymerized with thiophene (Th) to yield GO-f-PTAA-co-PTh. The synthesis of GO-f-PTAA and GO-f-PTAA-co-PTh composites is confirmed by Fourier transform infrared, ¹H-nuclear magnetic resonance, and X-ray photoelectron spectroscopies. The composites show better electrochemical properties than pure PTAA and superior solubility in organic solvents compared to pure GO. Using the soluble GO-f-PTAA and GO-f-PTAA-co-PTh composites, air-operable actuators are fabricated and their actuation performance is investigated. The copolymer-functionalized GO actuator exhibits good electroactive actuation behavior between 2 and 4 V, mainly because of the enhanced electrochemical performance of the composites, whereas the pure PTAA and GO-f-PTAA actuators do not show actuation under the applied voltage. The soluble conducting polymer-functionalized graphene composites developed in this study have potential applications in the fabrication of actuators that can be operated in air.