Issue 6, 2013
From the journal:

Journal of Materials Chemistry A

Facile fabrication and some specific properties of polymeric/inorganic bilayer hybrid hollow spheres

Rui Gao,a   Min Chen,a   Wei Li,a   Shuxue Zhoua  and  Limin Wu*a  

* Corresponding authors

a Department of Materials Science, and State Key Laboratory of Molecular Engineering of Polymers, Advanced Materials Laboratory, the Advanced Coatings Research Center of MEC, Fudan University, Shanghai 200433, PR. China
E-mail: lmw@fudan.edu.cn
Web: http://mse.fudan.edu.cn/wlm/english

Abstract

This paper presents a general and feasible method for the fabrication of polymer/inorganic bilayer hybrid hollow spheres, such as PSAA/ZrO2, PSAA/Nb2O5, PSAA/Ta2O5 and PSAM/TiO2. The formation process of these hybrid hollow spheres could be elucidated using a mechanism similar to the Kirkendall effect. With PSAM/TiO2 hybrid hollow spheres, the as-obtained hybrid hollow spheres showed tunable surface properties, high UV-Vis-NIR reflectance, low thermal conductivity and good compatibility to polymers, which gives them some interesting applications like solar-reflective heat-insulating coatings.

Graphical abstract: Facile fabrication and some specific properties of polymeric/inorganic bilayer hybrid hollow spheres

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Article information

DOI
https://doi.org/10.1039/C2TA00837H
Article type
Paper
Submitted
25 Oct 2012
Accepted
06 Dec 2012
First published
07 Dec 2012

J. Mater. Chem. A, 2013,1, 2183-2191

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Facile fabrication and some specific properties of polymeric/inorganic bilayer hybrid hollow spheres

R. Gao, M. Chen, W. Li, S. Zhou and L. Wu, J. Mater. Chem. A, 2013, 1, 2183 DOI: 10.1039/C2TA00837H

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