Supramolecular metallogels constructed from carboxylate gelators

Abstract

Serendipity still plays a role in gel discovery as the prediction of gel formation is difficult. This work explores the role of ligand, metal salt, solvent, and temperature in the formation of a low molecular mass carboxylate iron(III) system. The influence of each component is discussed. The gels obtained were characterised using thermal analysis, Fourier transform-infrared spectroscopy, powder X-ray diffraction, scanning electron microscopy, elemental analysis, microwave plasma-atomic emission spectroscopy, and inductively coupled plasma optical emission spectrometry. The response to external stimuli, including dye and gas sorption was examined.