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Issue 9, 2016
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Dispersion of PMMA-grafted, mesoscopic iron-oxide rods in polymer films

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Abstract

This study investigates the parameters that affect the dispersion of polymer grafted mesoscopic iron-oxide rods (FeMRs) in polymer matrices. FeMRs (212 nm long by 36 nm in diameter) are grafted with poly(methyl methacrylate) (PMMA) at three different brush molecular weights: 3.7 kg mol−1, 32 kg mol−1, and 160 kg mol−1. Each FeMR sample was cast in a polymer thin film consisting of either PMMA or poly(ethylene oxide) (PEO) each at a molecular weight much higher or much lower than the brush molecular weight. We find that the FeMRs with 160 kg mol−1 brush disperse in all matrices while the FeMRs with 32 kg mol−1 and 3.7 kg mol−1 brushes aggregate in all matrices. We perform simple free energy calculations, taking into account steric repulsion from the brush and van der Waals attraction between FeMRs. We find that there is a barrier for aggregation for the FeMRs with the largest brush, while there is no barrier for the other FeMRs. Therefore, for these mesoscopic particles, the brush size is the main factor that determines the dispersion state of FeMRs in polymer matrices with athermal or weakly attractive brush-matrix interactions. These studies provide new insight into the mechanisms that affect dispersion in polymer matrices of mesoscopic particles and therefore guide the design of composite films with well-dispersed mesoscopic particles.

Graphical abstract: Dispersion of PMMA-grafted, mesoscopic iron-oxide rods in polymer films

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Publication details

The article was received on 02 Oct 2015, accepted on 22 Jan 2016 and first published on 25 Jan 2016


Article type: Paper
DOI: 10.1039/C5SM02460A
Citation: Soft Matter, 2016,12, 2550-2556
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    Dispersion of PMMA-grafted, mesoscopic iron-oxide rods in polymer films

    R. C. Ferrier, Y. Huang, K. Ohno and R. J. Composto, Soft Matter, 2016, 12, 2550
    DOI: 10.1039/C5SM02460A

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