Issue 4, 2013
From the journal:

Chemical Science

Cross coupling of thioethers with aryl boroxines to construct biarylsvia Rh catalyzed C–S activation†

Fei Pan,a   Hui Wang,b   Peng-Xiang Shen,a   Jing Zhaob  and  Zhang-Jie Shi*ac  

* Corresponding authors

a Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry, Molecular Engineering of Education College of Chemistry, Green Chemistry Center, Peking University, Beijing 100871, China
E-mail: zshi@pku.edu.cn
Fax: +86-010-62760890
Tel: +86-010-62760890

b Nano-Micro Materials Research Center, School of Chemical Biology and Biotechnology, Peking University Shenzhen Graduate School, Shenzhen 518055, China

c State Key Laboratory of Organometallic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Abstract

A novel rhodium-catalyzed C–C bond formation was developed to construct biaryls through unreactive aryl C–S bond cleavage of thioethers with aryl boroxines. This protocol provided a supplemental method of traditional Suzuki–Miyaura coupling.

Graphical abstract: Cross coupling of thioethers with aryl boroxines to construct biaryls via Rh catalyzed C–S activation

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Article information

DOI
https://doi.org/10.1039/C3SC22242J
Article type
Edge Article
Submitted
15 Dec 2012
Accepted
08 Feb 2013
First published
11 Feb 2013

Chem. Sci., 2013,4, 1573-1577

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Cross coupling of thioethers with aryl boroxines to construct biaryls via Rh catalyzed C–S activation

F. Pan, H. Wang, P. Shen, J. Zhao and Z. Shi, Chem. Sci., 2013, 4, 1573 DOI: 10.1039/C3SC22242J

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