Jump to main content
Jump to site search

Issue 10, 2012
Previous Article Next Article

Allenoate-derived 1,5-, 1,7-, and 1,9-zwitterions as highly versatile coupling-partners for phosphine-triggered cycloaddition reactions

Author affiliations

Abstract

Our computational and experimental studies show that the high order 1,n-zwitterionic intermediates (n = 5, 7 and 9) of allenoate-PR3 are real species. The cycloaddition reactions of these versatile intermediates with electrophilic-coupling partners provide novel and highly convergent synthetic approaches to medium- and large-ring compounds.

Graphical abstract: Allenoate-derived 1,5-, 1,7-, and 1,9-zwitterions as highly versatile coupling-partners for phosphine-triggered cycloaddition reactions

Back to tab navigation

Supplementary files

Publication details

The article was received on 04 Feb 2012, accepted on 12 Jul 2012 and first published on 12 Jul 2012


Article type: Edge Article
DOI: 10.1039/C2SC20805A
Citation: Chem. Sci., 2012,3, 3053-3057
  •   Request permissions

    Allenoate-derived 1,5-, 1,7-, and 1,9-zwitterions as highly versatile coupling-partners for phosphine-triggered cycloaddition reactions

    W. Meng, H. Zhao, J. Nie, Y. Zheng, A. Fu and J. Ma, Chem. Sci., 2012, 3, 3053
    DOI: 10.1039/C2SC20805A

Search articles by author

Spotlight

Advertisements