Issue 34, 2016
From the journal:

RSC Advances

A new boat-like tungstoarsenate functionalized by carboxyethyltin and its catalytic properties†

Li-Ping Ji,a   Jing Du,a   Jian-Sheng Li,a   Lan-Cui Zhang,*a   Xiao-Jing Sang,*ab   He Yang,a   Hong-Juan Cuia  and  Zai-Ming Zhu*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, China
E-mail: zhanglancui@lnnu.edu.cn, sangxj923@nenu.edu.cn

b Centre of Analytical Test, Liaoning Normal University, Dalian 116029, China

Abstract

A new polyoxometalate (POM) estertin derivative, {C(NH2)3}Na10K7[(W4O16){Sn(CH2)2COO}4(B-α-AsW9O33)2]·25H2O (1), has been synthesized from K14[As2W19O67(H2O)]·nH2O ({As2W19}) and Cl3SnCH2CH2COOCH3, which exhibits an unusual boat-like structural feature: four [Sn(CH2)2COO]2+ groups surround a center W4O16 cluster and link two [AsW9O33]9− subunits. 1 shows efficient oxidation catalytic activity and can be applied for mimicking enzyme catalysis.

Graphical abstract: A new boat-like tungstoarsenate functionalized by carboxyethyltin and its catalytic properties

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Article information

DOI
https://doi.org/10.1039/C5RA27781G
Article type
Communication
Submitted
26 Dec 2015
Accepted
11 Mar 2016
First published
14 Mar 2016

RSC Adv., 2016,6, 28956-28959

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A new boat-like tungstoarsenate functionalized by carboxyethyltin and its catalytic properties

L. Ji, J. Du, J. Li, L. Zhang, X. Sang, H. Yang, H. Cui and Z. Zhu, RSC Adv., 2016, 6, 28956 DOI: 10.1039/C5RA27781G

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