Issue 110, 2015
From the journal:

RSC Advances

Highly efficient dehydrogenative cross-coupling of aldehydes with amines and alcohols†

Ramesh Deshidi,a   Masood Ahmad Rizvib  and  Bhahwal Ali Shah*a  

* Corresponding authors

a Academy of Scientific and Innovative Research (AcSIR), Natural Product Microbes, CSIR-Indian Institute of Integrative Medicine, Canal Road, Jammu-Tawi, India
E-mail: bashah@iiim.ac.in

b Department of Chemistry, University of Kashmir, Srinagar, India

Abstract

A common protocol for the synthesis of amides, esters and α-ketoesters via cross dehydrogenative coupling of aldehydes and amines/alcohols has been developed. The method is applicable to a wide variety of alcohols and amines as well as aliphatic and aromatic aldehydes. Also, the use of acetaldehyde for acetylation and ethyl glyoxalate to access 2-oxo-amino esters is presented for the first time.

Graphical abstract: Highly efficient dehydrogenative cross-coupling of aldehydes with amines and alcohols

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Article information

DOI
https://doi.org/10.1039/C5RA17425B
Article type
Communication
Submitted
28 Aug 2015
Accepted
16 Oct 2015
First published
16 Oct 2015

RSC Adv., 2015,5, 90521-90524

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Highly efficient dehydrogenative cross-coupling of aldehydes with amines and alcohols

R. Deshidi, M. A. Rizvi and B. A. Shah, RSC Adv., 2015, 5, 90521 DOI: 10.1039/C5RA17425B

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