Issue 5, 2014

Experimental and theoretical studies on nickel–zinc-catalyzed cross-coupling of gem-dibromoalkenes with P(O)–H compounds

Abstract

A new stereoselective one-pot protocol for the preparation of E-alkenyl-phosphorus compounds under catalysis of an inexpensive nickel–zinc catalyst system has been developed, which provides a potential useful method for C–P bond formation. 31P NMR spectrum and density functional theory calculations were performed to study the reaction mechanism.

Graphical abstract: Experimental and theoretical studies on nickel–zinc-catalyzed cross-coupling of gem-dibromoalkenes with P(O)–H compounds

Supplementary files

Article information

Article type
Communication
Submitted
18 Sep 2013
Accepted
14 Nov 2013
First published
21 Nov 2013

RSC Adv., 2014,4, 2322-2326

Experimental and theoretical studies on nickel–zinc-catalyzed cross-coupling of gem-dibromoalkenes with P(O)–H compounds

L. L. Liu, Y. Lv, Y. Wu, X. Gao, Z. Zeng, Y. Gao, G. Tang and Y. Zhao, RSC Adv., 2014, 4, 2322 DOI: 10.1039/C3RA45212C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements