Issue 5, 2014
From the journal:

RSC Advances

Experimental and theoretical studies on nickel–zinc-catalyzed cross-coupling of gem-dibromoalkenes with P(O)–H compounds†

Liu Leo Liu,a   Ye Lv,a   Yile Wu,a   Xiang Gao,b   Zhiping Zeng,b   Yuxing Gao,*a   Guo Tang*a  and  Yufen Zhaoa  

* Corresponding authors

a Department of Chemistry, College of Chemistry and Chemical Engineering, Key Laboratory for Chemical Biology of Fujian Province, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Xiamen University, Xiamen 361005, Fujian, China
E-mail: t12g21@xmu.edu.cn, gaoxingchem@xmu.edu.cn
Web: http://chem.xmu.edu.cn/group/yfzhao/zhao-home.html

b School of Pharmaceutical Sciences, Xiamen University, Xiamen 361102, Fujian, China

Abstract

A new stereoselective one-pot protocol for the preparation of E-alkenyl-phosphorus compounds under catalysis of an inexpensive nickel–zinc catalyst system has been developed, which provides a potential useful method for C–P bond formation. 31P NMR spectrum and density functional theory calculations were performed to study the reaction mechanism.

Graphical abstract: Experimental and theoretical studies on nickel–zinc-catalyzed cross-coupling of gem-dibromoalkenes with P(O)–H compounds

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Article information

DOI
https://doi.org/10.1039/C3RA45212C
Article type
Communication
Submitted
18 Sep 2013
Accepted
14 Nov 2013
First published
21 Nov 2013

RSC Adv., 2014,4, 2322-2326

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Experimental and theoretical studies on nickel–zinc-catalyzed cross-coupling of gem-dibromoalkenes with P(O)–H compounds

L. L. Liu, Y. Lv, Y. Wu, X. Gao, Z. Zeng, Y. Gao, G. Tang and Y. Zhao, RSC Adv., 2014, 4, 2322 DOI: 10.1039/C3RA45212C

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