Issue 1, 2014

Chlorotrimethylsilane (TMSCl): an efficient silicon-based Lewis acid mediator in allylic alkylation using a diethylzinc reagent

Abstract

Chlorotrimethylsilane (TMSCl) was a highly efficient catalyst in the allylic alkylation of 1,3-diaryl-2-propenyl acetates with a diethylzinc reagent, in which various 1,3-diaryl-2-propenyl acetates are efficiently transferred to 1,3-diarylpent-1-enes in good to excellent yields.

Graphical abstract: Chlorotrimethylsilane (TMSCl): an efficient silicon-based Lewis acid mediator in allylic alkylation using a diethylzinc reagent

Supplementary files

Article information

Article type
Communication
Submitted
31 Aug 2013
Accepted
31 Oct 2013
First published
05 Nov 2013

RSC Adv., 2014,4, 479-483

Chlorotrimethylsilane (TMSCl): an efficient silicon-based Lewis acid mediator in allylic alkylation using a diethylzinc reagent

W. Deng, F. Ye, X. Bai, L. Li, T. Song, Y. Wei and L. Xu, RSC Adv., 2014, 4, 479 DOI: 10.1039/C3RA44742A

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