Issue 39, 2013
From the journal:

RSC Advances

HMF derivatives as platform molecules: aqueous Baylis–Hillman reaction of glucosyloxymethyl-furfural towards new biobased acrylates†

Jia-Neng Tan,ab   Mohammed Ahmarab  and  Yves Queneau*ab  

* Corresponding authors

a INSA Lyon, ICBMS, Bâtiment J. Verne, 20 av A. Einstein, F-69621 Villeurbanne, France
E-mail: yves.queneau@insa-lyon.fr

b CNRS, UMR 5246, ICBMS, Université Lyon 1, INSA-Lyon, CPE-Lyon, Bâtiment CPE, 43 bd du 11 novembre 1918, F-69622 Villeurbanne, France

Abstract

A new type of biobased acrylates has been synthesized by a Baylis–Hillman reaction of alkylacrylates with α-D-glucosyloxymethyl-furfural (α-GMF), available in one step from isomaltulose. The reaction, performed in aqueous medium, was extended to other α,β-unsaturated substrates. The use of dimethylisosorbide as co-solvent was investigated.

Graphical abstract: HMF derivatives as platform molecules: aqueous Baylis–Hillman reaction of glucosyloxymethyl-furfural towards new biobased acrylates

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Article information

DOI
https://doi.org/10.1039/C3RA43369B
Article type
Communication
Submitted
06 Jun 2013
Accepted
09 Jul 2013
First published
10 Jul 2013

RSC Adv., 2013,3, 17649-17653

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HMF derivatives as platform molecules: aqueous Baylis–Hillman reaction of glucosyloxymethyl-furfural towards new biobased acrylates

J. Tan, M. Ahmar and Y. Queneau, RSC Adv., 2013, 3, 17649 DOI: 10.1039/C3RA43369B

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