Issue 37, 2013
From the journal:

RSC Advances

Time-resolved X-ray crystal structure analysis for elucidating the hidden ‘over-neutralized’ phase of TTF-CA†

Manabu Hoshino,*ab   Shunsuke Nozawa,c   Tokushi Sato,c   Ayana Tomita,c   Shin-ichi Adachicd  and  Shin-ya Koshiharaab  

* Corresponding authors

a Department of Chemistry and Materials Science, Tokyo Institute of Technology, Meguro-ku, Tokyo 152-8551, Japan
E-mail: mhoshino@chem.titech.ac.jp
Fax: +81 3 5734 2449
Tel: +81 3 5734 2449

b CREST, Japan Science and Technology Agency (JST), Japan

c Photon Factory, High Energy Accelerator Research Organization, Tsukuba, Ibaraki 305-0801, Japan

d PRESTO, Japan Science and Technology Agency (JST), Japan

Abstract

Photoinduced structural dynamics in tetrathiafulvalene-p-chloranil (TTF-CA) was directly observed by time-resolved X-ray crystal structure analysis. Temporal deformation corresponded to stepwise relaxation of intermolecular interactions and represented the generation of a more neutralized phase of TTF-CA than the initial one.

Graphical abstract: Time-resolved X-ray crystal structure analysis for elucidating the hidden ‘over-neutralized’ phase of TTF-CA

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Article information

DOI
https://doi.org/10.1039/C3RA42489H
Article type
Communication
Submitted
21 May 2013
Accepted
22 Jul 2013
First published
14 Aug 2013

RSC Adv., 2013,3, 16313-16317

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Time-resolved X-ray crystal structure analysis for elucidating the hidden ‘over-neutralized’ phase of TTF-CA

M. Hoshino, S. Nozawa, T. Sato, A. Tomita, S. Adachi and S. Koshihara, RSC Adv., 2013, 3, 16313 DOI: 10.1039/C3RA42489H

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