Issue 33, 2012
From the journal:

RSC Advances

Identification of (phosphine)gold(i) hydrates and their equilibria in wet solutions†

Yu Tanga  and  Biao Yu*a  

* Corresponding authors

a State Key Laboratory of Bioorganic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China
E-mail: byu@mail.sioc.ac.cn
Fax: (0086)-21-64166128

Abstract

The elusive gold(I) hydrates [Ph3PAu(OH2)]+TfO− and [((Ph3PAu)2OH)2]2+(TfO−)2 resulting from the most common gold(I) pre-catalyst Ph3PAuOTf have been characterized, leading to disclosure of the equilibria between gold oxo species in wet solutions.

Graphical abstract: Identification of (phosphine)gold(i) hydrates and their equilibria in wet solutions

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Article information

DOI
https://doi.org/10.1039/C2RA22282E
Article type
Communication
Submitted
25 Sep 2012
Accepted
23 Oct 2012
First published
23 Oct 2012

RSC Adv., 2012,2, 12686-12689

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Identification of (phosphine)gold(I) hydrates and their equilibria in wet solutions

Y. Tang and B. Yu, RSC Adv., 2012, 2, 12686 DOI: 10.1039/C2RA22282E

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