Issue 24, 2012
From the journal:

RSC Advances

Oxidative rearrangement of indoles to oxindoles†

Wesley J. Moran,*a   Kerry L. MacRorya  and  Arantxa Rodríguez*a  

* Corresponding authors

a Department of Chemical & Biological Sciences, University of Huddersfield, Queensgate, Huddersfield HD1 3DH, UK
E-mail: w.j.moran@hud.ac.uk, a.r.menendez@hud.ac.uk
Tel: +44 (0)1484 473741

Abstract

An unexpected oxidative rearrangement was observed when indoles substituted with 2-hydroxymalonates were subjected to typical iodination conditions. This unusual and unprecedented transformation is successful for a number of derivatives.

Graphical abstract: Oxidative rearrangement of indoles to oxindoles

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Article information

DOI
https://doi.org/10.1039/C2RA21800C
Article type
Communication
Submitted
13 Aug 2012
Accepted
15 Aug 2012
First published
16 Aug 2012

RSC Adv., 2012,2, 8962-8964

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Oxidative rearrangement of indoles to oxindoles

W. J. Moran, K. L. MacRory and A. Rodríguez, RSC Adv., 2012, 2, 8962 DOI: 10.1039/C2RA21800C

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