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Issue 27, 2012
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Synthesis of the C45–C53 tetrahydropyran domain of norhalichondrins and the C14–C22 tetrahydrofuran domain of the halichondrin family

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Abstract

Sequential asymmetric α-aminoxylation of aldehydes and Horner–Wadsworth–Emmons olefination has been used as the key reaction for the synthesis of the C45–C53 tetrahydropyran domain of norhalichondrins and C14–C22 tetrahydrofuran domain of halichondrin family.

Graphical abstract: Synthesis of the C45–C53 tetrahydropyran domain of norhalichondrins and the C14–C22 tetrahydrofuran domain of the halichondrin family

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Publication details

The article was received on 03 Jul 2012, accepted on 02 Sep 2012 and first published on 04 Sep 2012


Article type: Communication
DOI: 10.1039/C2RA21346J
Citation: RSC Adv., 2012,2, 10157-10159
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    Synthesis of the C45–C53 tetrahydropyran domain of norhalichondrins and the C14–C22 tetrahydrofuran domain of the halichondrin family

    G. Sabitha, G. Chandrashekhar, J. S. Yadav, K. Rachineni and B. Jagadeesh, RSC Adv., 2012, 2, 10157
    DOI: 10.1039/C2RA21346J

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