Cu(I)-Catalyzed stereoselective synthesis of trisubstituted Z-enol esters via interrupting the 1,3-O-transposition reaction

Changyuan Zhang; Lianfen Chen; Kai Chen; Chuntao Wang; Zurong Xu; Huanfeng Jiang; Shifa Zhu

doi:10.1039/C8QO00664D

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Cu(i)-Catalyzed stereoselective synthesis of trisubstituted Z-enol esters via interrupting the 1,3-O-transposition reaction†

Changyuan Zhang,^a Lianfen Chen,

^a Kai Chen,^a Chuntao Wang,^a Zurong Xu,^a Huanfeng Jiang

^a and Shifa Zhu

*^a

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* Corresponding authors

^a Key Laboratory of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, P. R. China
E-mail: zhusf@scut.edu.cn

Abstract

An efficient Cu(I)-catalyzed stereoselective synthesis of trisubstituted Z-enol esters via interrupting the 1,3-O-transposition process is reported. This method provided a convenient approach to highly functionalized Z-enol esters with mild reaction conditions and wide substrate scope.

This article is part of the themed collections: Celebrating the 90th birthday of Professor Lu Xiyan and Organic Chemistry Frontiers HOT articles for 2018

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DOI: https://doi.org/10.1039/C8QO00664D
Article type: Research Article
Submitted: 04 Jul 2018
Accepted: 16 Jul 2018
First published: 18 Jul 2018

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Org. Chem. Front., 2018,5, 2510-2514

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Cu(I)-Catalyzed stereoselective synthesis of trisubstituted Z-enol esters via interrupting the 1,3-O-transposition reaction

C. Zhang, L. Chen, K. Chen, C. Wang, Z. Xu, H. Jiang and S. Zhu, Org. Chem. Front., 2018, 5, 2510 DOI: 10.1039/C8QO00664D

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Organic Chemistry Frontiers

Cu(i)-Catalyzed stereoselective synthesis of trisubstituted Z-enol esters via interrupting the 1,3-O-transposition reaction†

Abstract

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Cu(I)-Catalyzed stereoselective synthesis of trisubstituted Z-enol esters via interrupting the 1,3-O-transposition reaction

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