Issue 9, 2017
From the journal:

Organic Chemistry Frontiers

Ionic liquids are not innocent in Pd catalysis. C–H arylation of thiazolium and imidazolium ionic liquids with aryl halides†

Takahide Fukuyama, ORCID logo *a   Md. Taifur Rahman,a   Hiroshi Mashima,a   Hideo Takahashia  and  Ilhyong Ryu*ab  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan
E-mail: fukuyama@c.s.osakafu-u.ac.jp, ryu@c.s.osakafu-u.ac.jp

b Department of Applied Chemistry, National Chiao Tung University, Hsinchu 30010, Taiwan

Abstract

The ionic liquids bearing an aromatic vinylic C–H moiety are not innocent during Pd-catalyzed cross-coupling reactions of aryl halides, since palladium-catalyzed direct C–H arylation of thiazolium and imidazolium ionic liquids competes.

Graphical abstract: Ionic liquids are not innocent in Pd catalysis. C–H arylation of thiazolium and imidazolium ionic liquids with aryl halides

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Article information

DOI
https://doi.org/10.1039/C7QO00331E
Article type
Research Article
Submitted
26 Apr 2017
Accepted
17 Jun 2017
First published
19 Jun 2017

Org. Chem. Front., 2017,4, 1863-1866

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Ionic liquids are not innocent in Pd catalysis. C–H arylation of thiazolium and imidazolium ionic liquids with aryl halides

T. Fukuyama, Md. T. Rahman, H. Mashima, H. Takahashi and I. Ryu, Org. Chem. Front., 2017, 4, 1863 DOI: 10.1039/C7QO00331E

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