Issue 3, 2017
From the journal:

Organic Chemistry Frontiers

Palladium-catalyzed cascade reaction of haloalkynes with unactivated alkenes for assembly of functionalized oxetanes†

Jianxiao Li,a   Weigao Hu,a   Chunsheng Li,a   Shaorong Yang,a   Wanqing Wu*a  and  Huanfeng Jiang*a  

* Corresponding authors

a Key Laboratory of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China
E-mail: cewuwq@scut.edu.cn, jianghf@scut.edu.cn
Fax: +86-20-87112906
Tel: +86-20-87112906

Abstract

A novel and efficient palladium-catalyzed aerobic cascade reaction of haloalkynes with unactivated alkenes for synthesis of functionalized oxetanes has been demonstrated. This cascade protocol, including chloropalladation and a Heck-like process, proceeds smoothly with good functional group tolerance and high selectivity.

Graphical abstract: Palladium-catalyzed cascade reaction of haloalkynes with unactivated alkenes for assembly of functionalized oxetanes

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Article information

DOI
https://doi.org/10.1039/C6QO00633G
Article type
Research Article
Submitted
15 Oct 2016
Accepted
09 Dec 2016
First published
12 Dec 2016

Org. Chem. Front., 2017,4, 373-376

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Palladium-catalyzed cascade reaction of haloalkynes with unactivated alkenes for assembly of functionalized oxetanes

J. Li, W. Hu, C. Li, S. Yang, W. Wu and H. Jiang, Org. Chem. Front., 2017, 4, 373 DOI: 10.1039/C6QO00633G

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