Issue 7, 2015
From the journal:

Organic Chemistry Frontiers

Palladium catalyzed amide-oxazoline directed C–H acetoxylation of arenes†

Bin Liu,a   Xuhu Huang,a   Xin Wang,a   Zemei Ge*a  and  Runtao Li*a  

* Corresponding authors

a Skate Key Laboratory of Natural and Biomimetic Drugs, Peking University, Beijing 100191, China
E-mail: lirt@bjmu.edu.cn

Abstract

Herein we reported a Pd-catalyzed ortho-acetoxylation of arenes through a six-membered system using an amide-oxazoline as the directing group. A wide range of aryls and heteroaryls are tolerated. The approach provides general and straightforward access to phenol esters without the need for extra oxidants.

Graphical abstract: Palladium catalyzed amide-oxazoline directed C–H acetoxylation of arenes

About
Cited by
Related
Download options Please wait...

Associated articles

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5QO00104H
Article type
Research Article
Submitted
31 Mar 2015
Accepted
28 Apr 2015
First published
29 Apr 2015

Org. Chem. Front., 2015,2, 797-800

Permissions

Request permissions

Palladium catalyzed amide-oxazoline directed C–H acetoxylation of arenes

B. Liu, X. Huang, X. Wang, Z. Ge and R. Li, Org. Chem. Front., 2015, 2, 797 DOI: 10.1039/C5QO00104H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements