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Issue 6, 2016
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Light induced catalytic hydrodefluorination of perfluoroarenes by porphyrin rhodium

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Abstract

Photocatalytic hydrodefluorination of perfluoroarenes by rhodium porphyrin complexes with high tolerance to various functional groups has been developed. Mechanistic studies reveal that the rhodium aryl complex, (por)Rh-C6F4R, is the key intermediate.

Graphical abstract: Light induced catalytic hydrodefluorination of perfluoroarenes by porphyrin rhodium

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Publication details

The article was received on 01 Dec 2015, accepted on 31 Mar 2016 and first published on 05 Apr 2016


Article type: Research Article
DOI: 10.1039/C5QI00269A
Author version available: Download Author version (PDF)
Citation: Inorg. Chem. Front., 2016,3, 861-865
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    Light induced catalytic hydrodefluorination of perfluoroarenes by porphyrin rhodium

    X. Liu, Z. Wang, X. Zhao and X. Fu, Inorg. Chem. Front., 2016, 3, 861
    DOI: 10.1039/C5QI00269A

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