Issue 2, 2015

Planar trinuclear complexes with linear arrays of metal ions

Abstract

Two trinuclear complexes, [CuII3(L)2](BF4)2 (1) and [NiII3(L)2(MeOH)4](BF4)2 (2), supported by the multidentate ligand L2− (H2L = 5,5′-pyridyl-3,3′-bi-1H-pyrazole) were obtained and their structures determined. Both complexes have linear trinuclear structures composed of two ligands and three metal ions. Cryomagnetic studies reveal that both complexes show intramolecular antiferromagnetic interactions between the metal ions.

Graphical abstract: Planar trinuclear complexes with linear arrays of metal ions

Supplementary files

Article information

Article type
Research Article
Submitted
21 Oct 2014
Accepted
22 Dec 2014
First published
26 Dec 2014

Inorg. Chem. Front., 2015,2, 125-128

Author version available

Planar trinuclear complexes with linear arrays of metal ions

S. Terashima, G. N. Newton, T. Shiga and H. Oshio, Inorg. Chem. Front., 2015, 2, 125 DOI: 10.1039/C4QI00172A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements