Issue 45, 2017
From the journal:

Polymer Chemistry

Probing the first steps of photoinduced free radical polymerization at water–oil interfaces†

Denisa Darvasiová,a   Zuzana Barberiková,a   Anna Eibel, ORCID logo b   Max Schmallegger,b   Georg Gescheidt, ORCID logo b   Michal Zalibera ORCID logo *a  and  Dmytro Neshchadin ORCID logo *b  

* Corresponding authors

a Institute of Physical Chemistry and Chemical Physics, Slovak University of Technology, Radlinského 9, 812 37 Bratislava 1, Slovakia
E-mail: michal.zalibera@stuba.sk

b Institute of Physical and Theoretical Chemistry, Graz University of Technology, NAWI Graz, Stremayrgasse 9, 8010 Graz, Austria
E-mail: neshchadin@tugraz.at

Abstract

Phosphanoyl radicals, produced by α-photocleavage of exclusively octane-soluble acylphosphane oxides, rapidly react with both water- and octane-soluble monomers in water-in-octane microemulsions. The presented mechanistic insights open the possibility for the tailored construction of photo-generated copolymers comprising polar and non-polar blocks at the same time.

Graphical abstract: Probing the first steps of photoinduced free radical polymerization at water–oil interfaces

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Article information

DOI
https://doi.org/10.1039/C7PY01414G
Article type
Communication
Submitted
21 Aug 2017
Accepted
30 Oct 2017
First published
31 Oct 2017

Polym. Chem., 2017,8, 6943-6947

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Probing the first steps of photoinduced free radical polymerization at water–oil interfaces

D. Darvasiová, Z. Barberiková, A. Eibel, M. Schmallegger, G. Gescheidt, M. Zalibera and D. Neshchadin, Polym. Chem., 2017, 8, 6943 DOI: 10.1039/C7PY01414G

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