Issue 20, 2016

Styrenic DABCO salt-containing monomers for the synthesis of novel charged polymers

Abstract

A facile, two-step synthesis afforded styrenic DABCO salt monomers bearing two cyclic quaternary ammonium cations. Free radical polymerization of the DABCO salt monomers yielded homopolymers and copolymers with n-butyl acrylate. DABCO salt-containing ionomers exhibited superior thermomechanical properties with extended plateau regimes compared to ionomers bearing singly-charged pendant groups.

Graphical abstract: Styrenic DABCO salt-containing monomers for the synthesis of novel charged polymers

Supplementary files

Article information

Article type
Communication
Submitted
10 Mar 2016
Accepted
23 Apr 2016
First published
25 Apr 2016
This article is Open Access
Creative Commons BY-NC license

Polym. Chem., 2016,7, 3370-3374

Styrenic DABCO salt-containing monomers for the synthesis of novel charged polymers

K. Zhang, K. J. Drummey, N. G. Moon, W. D. Chiang and T. E. Long, Polym. Chem., 2016, 7, 3370 DOI: 10.1039/C6PY00426A

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