Amide-bridged ladder poly(p-phenylene) was synthesized in two steps, through the polycondensation of aromatic diamines and dicarboxylic acid derivatives followed by palladium-catalyzed intramolecular direct arylation. The π-stacked assembly of the polymer in solution was investigated along with the single crystal X-ray structure analysis of a model oligomer.
K. Takagi, R. Kato, S. Yamamoto and H. Masu, Polym. Chem., 2015, 6, 6792 DOI: 10.1039/C5PY01154J
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