Xanthate-mediated living/controlled radical copolymerization of hexafluoropropylene and butyl vinyl ether under 60Co γ-ray irradiation and preparation of fluorinated polymers end-capped with a fluoroalkyl sulfonic acid group

Pucheng Wang; Jingwen Dai; Lei Liu; Qibao Dong; Bangkun Jin; Ruke Bai

doi:10.1039/C3PY21158D

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Xanthate-mediated living/controlled radical copolymerization of hexafluoropropylene and butyl vinyl ether under ⁶⁰Co γ-ray irradiation and preparation of fluorinated polymers end-capped with a fluoroalkyl sulfonic acid group†

Pucheng Wang,^a Jingwen Dai,^a Lei Liu,^a Qibao Dong,^a Bangkun Jin*^a and Ruke Bai*^a

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* Corresponding authors

^a CAS Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026, People's Republic of China
E-mail: bairk@ustc.edu.cn
Fax: +86-551-3631760
Tel: +86-551-3600722

Abstract

Living/controlled radical copolymerization of hexafluoropropylene and butyl vinyl ether has been successfully achieved at room temperature under ⁶⁰Co γ-ray irradiation in the presence of ethyl 2-(ethoxycarbonothioylthio) acetate. The copolymer end-capped with a sulfonic acid group has been prepared by oxidation of the xanthate end group.

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Article information

DOI: https://doi.org/10.1039/C3PY21158D
Article type: Communication
Submitted: 31 Dec 2012
Accepted: 22 Jan 2013
First published: 23 Jan 2013

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Polym. Chem., 2013,4, 1760-1764

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Xanthate-mediated living/controlled radical copolymerization of hexafluoropropylene and butyl vinyl ether under ⁶⁰Co γ-ray irradiation and preparation of fluorinated polymers end-capped with a fluoroalkyl sulfonic acid group

P. Wang, J. Dai, L. Liu, Q. Dong, B. Jin and R. Bai, Polym. Chem., 2013, 4, 1760 DOI: 10.1039/C3PY21158D

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Polymer Chemistry