Issue 6, 2013

Enhanced stereocomplex formation of enantiomeric polylactides grafted on a polyrotaxane platform

Abstract

We report (i) synthesis of novel graft copolymers of a α-CD/PEG polyrotaxane (PRX) backbone and enantiomeric PLA side chains, PRX-g-PLLA and PRX-g-PDLA, (ii) selective stereocomplex formation on a movable PRX in the bulk state, and (iii) preparation of soft materials with continuous anisotropic phases by blending of the L- and D-isomers.

Graphical abstract: Enhanced stereocomplex formation of enantiomeric polylactides grafted on a polyrotaxane platform

Supplementary files

Article information

Article type
Communication
Submitted
01 Dec 2012
Accepted
28 Jan 2013
First published
08 Feb 2013

Polym. Chem., 2013,4, 1769-1773

Enhanced stereocomplex formation of enantiomeric polylactides grafted on a polyrotaxane platform

K. Nagahama, R. Aoki, T. Saito, T. Ouchi, Y. Ohya and N. Yui, Polym. Chem., 2013, 4, 1769 DOI: 10.1039/C3PY21055C

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