Issue 22, 2013
From the journal:

Polymer Chemistry

Ferrocene-based poly(aroxycarbonyltriazole)s: synthesis by metal-free click polymerization and use as precursors to magnetic ceramics†

Hongkun Li,ab   Lingzhi Li,a   Haiqiang Wu,a   Jacky W. Y. Lam,b   Jing Zhi Sun,a   Anjun Qin*a  and  Ben Zhong Tang*abc  

* Corresponding authors

a MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, China
E-mail: qinaj@zju.edu.cn, tangbenz@ust.hk
Fax: +86-571-87953734
Tel: +86-571-87953734

b Department of Chemistry, Institute for Advanced Study, Institute of Molecular Functional Materials, The Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong, China

c Guangdong Innovative Research Team, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640, China

Abstract

Ferrocene-based poly(aroxycarbonyltriazole)s with high molecular weights and regioregularities were prepared in high yields by the efficient metal-free click polymerization of dipropiolates and the ferrocene-containing diazide under mild reaction conditions. The resulting polytriazoles are redox active, and could be used as precursors to generate soft magnetic ceramics with high magnetizability and low coercivity when pyrolyzed at elevated temperatures.

Graphical abstract: Ferrocene-based poly(aroxycarbonyltriazole)s: synthesis by metal-free click polymerization and use as precursors to magnetic ceramics

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Article information

DOI
https://doi.org/10.1039/C3PY00892D
Article type
Communication
Submitted
08 Jul 2013
Accepted
27 Jul 2013
First published
31 Jul 2013

Polym. Chem., 2013,4, 5537-5541

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Ferrocene-based poly(aroxycarbonyltriazole)s: synthesis by metal-free click polymerization and use as precursors to magnetic ceramics

H. Li, L. Li, H. Wu, J. W. Y. Lam, J. Z. Sun, A. Qin and B. Z. Tang, Polym. Chem., 2013, 4, 5537 DOI: 10.1039/C3PY00892D

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