Issue 1, 2011
From the journal:

Polymer Chemistry

Synthesis and use of a new alkene-functionalized SG1-based alkoxyamine†

Claire Bernhardt,ab   François Stoffelbach*ab  and  Bernadette Charleux*c  

* Corresponding authors

a UPMC Univ. Paris 6, UMR 7610 Laboratoire de Chimie des Polymères, Place Jussieu, Tour 44-54, Paris Cedex 05, France
E-mail: francois.stoffelbach@upmc.fr

b CNRS Univ. Paris 6, UMR 7610 Laboratoire de Chimie des Polymères, Place Jussieu, Tour 44-54, Paris Cedex 05, France

c Université de Lyon, Univ. Lyon 1, CPE Lyon, CNRS UMR 5265, C2P2, Team LCPP Bat 308F, 43 Bd du 11 novembre 1918, Villeurbanne, France
E-mail: bernadette.charleux@lcpp.cpe.fr

Abstract

A new alkene-functionalized SG1-based alkoxyamine was synthesized and used to prepare well-defined functional polymers by nitroxide mediated polymerization. The latter were characterized by NMR, SEC and MALDI-TOF mass spectrometry. Livingness was assessed by chain extension toward AB-type block copolymer. The alkene functionality located at the α-chain-end allowed the post-modification of the polymer by thiol–ene coupling reaction.

Graphical abstract: Synthesis and use of a new alkene-functionalized SG1-based alkoxyamine

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Article information

DOI
https://doi.org/10.1039/C0PY00282H
Article type
Paper
Submitted
31 Aug 2010
Accepted
07 Oct 2010
First published
29 Oct 2010

Polym. Chem., 2011,2, 229-235

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Synthesis and use of a new alkene-functionalized SG1-based alkoxyamine

C. Bernhardt, F. Stoffelbach and B. Charleux, Polym. Chem., 2011, 2, 229 DOI: 10.1039/C0PY00282H

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