Issue 5, 2010
From the journal:

Polymer Chemistry

Redox-controlled ‘smart’ polyacrylamide solubility†

Hui Fu,a   Danielle M. Policarpio,a   James D. Batteas*a  and  David E. Bergbreiter*a  

* Corresponding authors

a Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, Texas, USA
E-mail: batteas@chem.tamu.edu, bergbreiter@tamu.edu

Abstract

“Smart” acrylamide copolymers containing N-isopropyl and 4-N-amino-2,2,6,6-tetramethylpiperidin-1-oxyl-4-yl (TEMPO) groups undergo reversible redox behavior leading to LCST changes. Oxidation (NaOCl/H2O) or reduction (ascorbic acid) changes the copolymer's LCST from 18 °C to 35–40 °C.

Graphical abstract: Redox-controlled ‘smart’ polyacrylamide solubility

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C0PY00060D
Article type
Communication
Submitted
23 Feb 2010
Accepted
26 Feb 2010
First published
24 Mar 2010

Polym. Chem., 2010,1, 631-633

Permissions

Request permissions

Redox-controlled ‘smart’ polyacrylamide solubility

H. Fu, D. M. Policarpio, J. D. Batteas and D. E. Bergbreiter, Polym. Chem., 2010, 1, 631 DOI: 10.1039/C0PY00060D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements