Issue 12, 2002
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Silicon–carbon bond cleavage of organosilicon amines MenN[CH2Si(OCH2CH2)3N]3–n (n = 1, 2) by phenols

Nataliya F. Lazareva,*a   Esfir I. Brodskayaa  and  Gennadii V. Ratovskya  

* Corresponding authors

a Institute of Chemistry, Siberian Division, Russian Academy of Sciences, 1 Faforsky Street, Irkutsk 664033, Russian Federation
E-mail: nata@irioch.irk.ru

Abstract

Anomalously high basicity of organosilicon amines MenN[CH2Si(OCH2CH2)3N]3–n determines the ease of nucleophilic cleavage of the Si–C bond by phenols even at room temperature. The conversion of silatrane increases both with phenol acidity and basicity of the exocyclic nitrogen atom.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B207208D
Article type
Paper
Submitted
23 Jul 2002
Accepted
18 Sep 2002
First published
25 Oct 2002

J. Chem. Soc., Perkin Trans. 2, 2002, 2083-2086

Permissions

Request permissions

Silicon–carbon bond cleavage of organosilicon amines MenN[CH2Si(OCH2CH2)3N]3–n (n = 1, 2) by phenols

N. F. Lazareva, E. I. Brodskaya and G. V. Ratovsky, J. Chem. Soc., Perkin Trans. 2, 2002, 2083 DOI: 10.1039/B207208D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements