Issue 9, 2000
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

The synthesis and characterization of 1′-bromo-1,2-methano[60]fullerene

Nita Dragoe,*a   Mitsuhiro Iwaya,a   Hidekazu Shimotania  and  Koichi Kitazawa*a  

* Corresponding authors

a Department of Applied Chemistry, University of Tokyo, Japan Science and Technology Corporation, CREST, Tokyo, Japan

Abstract

In this paper we report the synthesis and characterization of 1′-bromo-1,2-methano[60]fullerene. This methanofullerene was synthesized using the reaction of C60 with bromocarbene. The interest in this derivative is related to the possibility of its further functionalization via Suzuki coupling as well as it being a possible intermediate for the generation of a C61 unit.

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Article information

DOI
https://doi.org/10.1039/B003252M
Article type
Paper
Submitted
25 Apr 2000
Accepted
19 Jul 2000
First published
14 Aug 2000

J. Chem. Soc., Perkin Trans. 2, 2000, 1885-1888

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The synthesis and characterization of 1′-bromo-1,2-methano[60]fullerene

N. Dragoe, M. Iwaya, H. Shimotani and K. Kitazawa, J. Chem. Soc., Perkin Trans. 2, 2000, 1885 DOI: 10.1039/B003252M

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