SCHEDULED MAINTENANCE
The relative reactivities of cyclohexanones in which the 2-axial position is substituted by methyl or methoxy group in LiAlH4 reduction strongly support the Cieplak model which focuses on the importance of stabilisation of the transition state by antiperiplanar allylic bonds.
Y. Senda, S. Nakano, H. Kunii and H. Itoh, J. Chem. Soc., Perkin Trans. 2, 1993, 1009 DOI: 10.1039/P29930001009
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