Issue 12, 1985

Behaviour of 1,4,5-substituted tetrazolines under electron impact: unambiguous identification of tetrazolium ions by CAD/MIKE spectrometry

Abstract

The mass spectra of some 1,4,5-substituted tetrazolines were studied in order to establish the structure of the compounds. An unusual cleavage of the molecular ion of the 5-phenyl-substituted tetrazolines was observed, i.e. the loss of a phenyl radical leading to a tetrazolium ion. The tetrazolium ions undergo one or two cycloreversions, depending on whether the tetrazoline bears two similar or two different substituents on the cyclic nitrogen atoms, thus leading to the formation of one or two nitrilium ions.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1985, 1869-1872

Behaviour of 1,4,5-substituted tetrazolines under electron impact: unambiguous identification of tetrazolium ions by CAD/MIKE spectrometry

B. Carboni, R. Carrié, P. H. Lambert and P. Guenot, J. Chem. Soc., Perkin Trans. 2, 1985, 1869 DOI: 10.1039/P29850001869

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements