Issue 23, 2001

Synthesis of new chiral and nonchiral N2O2 and N2S2 tetradentate ligands and their metal complexes

Abstract

N,N′-Bis(3-aryl-3-oxoprop-1-enyl)diamines and N,N′-bis(3-aryl-3-thioxoprop-1-enyl)diamines are synthesised by condensation of chiral or nonchiral diamines on the corresponding functionalised ketoenolate 2 or dithiolylium salt 4. Complexation of the obtained N2O2 and N2S2 ligands with transition metals is investigated.

Graphical abstract: Synthesis of new chiral and nonchiral N2O2 and N2S2 tetradentate ligands and their metal complexes

Article information

Article type
Paper
Submitted
12 Sep 2001
Accepted
26 Oct 2001
First published
16 Nov 2001

J. Chem. Soc., Perkin Trans. 1, 2001, 3128-3131

Synthesis of new chiral and nonchiral N2O2 and N2S2 tetradentate ligands and their metal complexes

F. Mevellec, S. Collet, D. Deniaud, A. Reliquet and J. Meslin, J. Chem. Soc., Perkin Trans. 1, 2001, 3128 DOI: 10.1039/B108210H

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