The natural product SB-219383 1a contains an unique bicyclic hydroxyamino sugar moiety. Novel C-glycosidation reactions of this hydroxyamino sugar moiety are reported. The formation of a sugar nitrone intermediate is postulated which is subsequently trapped by electron-rich aromatic rings to yield C-aryl
J. M. Berge, C. S. V. Houge-Frydrych and R. L. Jarvest, J. Chem. Soc., Perkin Trans. 1, 2001, 2521 DOI: 10.1039/B105965N
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