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Issue 9, 2001
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exo-Glycals from glycosyl cyanides. First generation of C-glycosylmethylene carbenes from 2,5- and 2,6-anhydroaldose tosylhydrazones

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Abstract

In a one-pot reaction acylated glycosyl cyanides were transformed with Raney nickel–sodium hypophosphite into 2,5- and 2,6-anhydroaldose tosylhydrazones, which gave exo-glycals under Bamford–Stevens conditions.

Graphical abstract: exo-Glycals from glycosyl cyanides. First generation of C-glycosylmethylene carbenes from 2,5- and 2,6-anhydroaldose tosylhydrazones

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Publication details

The article was received on 03 Jan 2001, accepted on 02 Apr 2001 and first published on 18 Apr 2001


Article type: Communication
DOI: 10.1039/B102963K
Citation: J. Chem. Soc., Perkin Trans. 1, 2001,0, 942-943
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    exo-Glycals from glycosyl cyanides. First generation of C-glycosylmethylene carbenes from 2,5- and 2,6-anhydroaldose tosylhydrazones

    M. Tóth and L. Somsák, J. Chem. Soc., Perkin Trans. 1, 2001, 0, 942
    DOI: 10.1039/B102963K

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