Issue 22, 2000
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Cycloaddition reactions of 2-oxo-2H-cyclohepta[b]furan derivatives with arylacetylenes and the di-π-methane rearrangement of homobarrelene derivatives

Vijay Nair,*a   Mecheril Valsan Nandakumar,a   Gopinathan Nair Anilkumar,a   Davis Maliakal,a   Mariappanadar Vairamani,b   Sripadi Prabhakarb  and  Nigam P. Rathc  

* Corresponding authors

a Organic Chemistry Division, Regional Research Laboratory (CSIR), Trivandrum, India

b Analytical Chemistry Division, Indian Institute of Chemical Technology, Hyderabad, India

c Department of Chemistry, University of Missouri-St. Louis, Missouri, USA

Abstract

2-Oxo-2H-cyclohepta[b]furan derivatives participate in [4 + 2]cycloaddition reactions with aryl acetylenes leading to homobarrelene derivatives and the latter undergo di-π-methane rearrangement resulting in complex carbocycles.

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Article information

DOI
https://doi.org/10.1039/B005377P
Article type
Paper
Submitted
05 Jul 2000
Accepted
04 Sep 2000
First published
31 Oct 2000

J. Chem. Soc., Perkin Trans. 1, 2000, 3795-3798

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Cycloaddition reactions of 2-oxo-2H-cyclohepta[b]furan derivatives with arylacetylenes and the di-π-methane rearrangement of homobarrelene derivatives

V. Nair, M. V. Nandakumar, G. N. Anilkumar, D. Maliakal, M. Vairamani, S. Prabhakar and N. P. Rath, J. Chem. Soc., Perkin Trans. 1, 2000, 3795 DOI: 10.1039/B005377P

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