Issue 12, 2000
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

The synthesis of mono- and bicyclic ethersvia acid catalysed ring-opening cyclisation of tetrahydropyranyl ether derivatives

Darren J. Dixon,a   Steven V. Ley*a  and  Edward W. Tatea  

* Corresponding authors

a Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK

Abstract

A range of monocyclic and bicyclic alkenols were synthesised via acid catalysed ring-opening cyclisation of homoallylic tetrahydropyranyl ether derivatives in excellent yield. Upon palladium catalysed hydrogenation these products were reduced with excellent diastereoselectivity to the corresponding saturated cyclic alcohols in essentially quantitative yield.

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Article information

DOI
https://doi.org/10.1039/A909302H
Article type
Paper
Submitted
24 Nov 1999
Accepted
13 Apr 2000
First published
25 May 2000

J. Chem. Soc., Perkin Trans. 1, 2000, 1829-1836

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The synthesis of mono- and bicyclic ethers via acid catalysed ring-opening cyclisation of tetrahydropyranyl ether derivatives

D. J. Dixon, S. V. Ley and E. W. Tate, J. Chem. Soc., Perkin Trans. 1, 2000, 1829 DOI: 10.1039/A909302H

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