SCHEDULED MAINTENANCE
Mannoside-based dendrimers were prepared by tetrafold glycosidation of selenium-donors with branched alcohol scaffolds. A trisaccharide-based glycocluster could be assembled in one reaction vessel based on reactivity tuning of glycosyl fluorides, orthogonal coupling to a glycosyl selenide and subsequent capture onto the dendritic scaffold.
P. Langer, S. J. Ince and S. V. Ley, J. Chem. Soc., Perkin Trans. 1, 1998, 3913 DOI: 10.1039/A807621I
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